Sgas=KHP gas
Table 13.4 (probably wont need to memorize) and example 13.2
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Henry's law:
,An intermolecular forces exhibited by all atoms and molecules that result from
fluctuations in the electron distribution. These forces occur because of fluctuations on
the electron distribution within molecules or atoms. There is a fleeting charge
separation called an instantaneous dipole or temporary dipole, which attract other
instantaneous dipoles (positive attracts negative and vice versa).
- A larger electron cloud can result in a greater dispersion forces.
- Dispersion force increases with increasing molar mass.
- Molecules with a longer shape also have
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Dispersion forces:
K<<1 Reverse reaction is favored, forward reaction does not proceed very far.
K=(equals about)1 Neither direction is favored, forward reaction proceeds about
halfway.
K>>1 Forward reaction is favored; forward reaction proceeds essentially to
completion.
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The significance of the equilibrium constant:
A model for bonding in atomic solids based on molecular orbital theory, in which
atomic orbitals combine and become delocalized over the entire crystal.
-In semiconductors, there is a small energy gap, and in insulators, there is a large
energy gap. study table 12.2
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Band theory:
The number of moles of a component in a mixture divided by the total
number of moles in the mixture.
*mole percent: Multiply the mole fraction by 100%.
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Mole fraction:
Fullerenes: Carbon clusters, such as C 60, bonded in roughly spherical shapes
containing from 36 to over 100 carbon atoms.
Nanotubes: Long, tubular structures consisting of interconnected C 6 rings.
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Fullerenes and nanotubes:
The smallest divisible unit of a crystal that when repeated in 3D, reproduces the entire
crystal lattice.
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, Unit cell:
The conversion from a gas to a solid.
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Deposition:
The phase transition from a liquid to a gas.
-Liquids that have enough energy can transition to the gaseous state. This reverse also
occurs simultaneously.
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Vaporization:
Polar liquids tend to be miscible with water, while nonpolar liquids are not. "like
dissolves like"
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In general, polar liquids:
IM forces exist among all the particles that compose matter. The state of a sample of
matter- solid, liquid, or gas- depends on the magnitude of intermolecular forces