CHEM133
Final Exam Study Questions
Lessons 4-7
Lesson 4
1. Consider the following reaction:
A2 + B2 → 2AB ΔH = –321 kJ
Bond energy (A2) = 1/2AB
Bond energy (B2) =393 kJ/mol.
What is the numerical value for Bond energy (A2) ?
Question options:
554 kJ/mol
714 kJ/mol
-161 kJ/mol
238 kJ/mol
2. Element A has an electronegativity of 0.8 and element B has an
electronegativity of 3.0. Which statement best describes the bonding in
A3B?
Question options:
The compound is largely ionic with A as the anion.
The AB bond is largely covalent with a δ+ on A.
The compound is largely ionic with A as the cation.
The AB bond is largely covalent with a δ- on A.
3. Which is the longest bond?
Question options:
N-N
N≡N
All three bond lengths should be about the same.
N=N
4. Estimate the heat of combustion for one mole of acetylene:
, CHEM133
Final Exam Study Questions
Lessons 4-7
C2H2(g) + O2(g) → 2CO2(g) + H2O(g)
Bond Bond Energy (kJ/mol)
C≡C 839
C–H 413
O=O 495
C=O 799
O–H 467
Question options:
-1228 kJ
-447 kJ
365 kJ
1228 kJ
447 kJ
5. Which of the following groups contains no ionic compounds?
Question options:
NaH, CaF2, NaNH2
HCN, NO2, Ca(NO3)2
PCl5, LiBr, Zn(OH)2
CH2O, H2S, NH3
KOH, CCl4, SF4
6. In which case is the bond polarity incorrect?
Question options:
δ+Si–Sδ–
δ+H–Fδ–
δ+Mg–Hδ–
δ+Cl–Iδ–
δ+K–Oδ–
7. The electron pair in a C-F bond could be considered
Question options:
closer to C because carbon has a lower electronegativity than fluorine
, CHEM133
Final Exam Study Questions
Lessons 4-7
closer to C because carbon has a larger radius and thus exerts greater
control over the shared electron pair
centrally located directly between the C and F
an inadequate model since the bond is ionic
closer to F because fluorine has a higher electronegativity than
carbon
8. Which of the following bonds would be the most polar without being
considered ionic?
Question options:
N-O
C-O
O-O
Si-O
Mg-O
9. Which one of the following is most likely to be a covalent compound?
Question options:
CaO
Sr(NO3)2
NF3
CsOH
LiF
10. Which bond has the highest bond dissociation energy?
Question options:
All three bonds should have about the same dissociation energy.
N=N
N≡N
N-N
11. Calculate the lattice energy of NaBr(s), given the following
thermochemical equations, where ΔIE and ΔEA are ionization energy and
electron affinity, respectively.
Na(s) → Na(g) ΔHf° = +107 kJ
Final Exam Study Questions
Lessons 4-7
Lesson 4
1. Consider the following reaction:
A2 + B2 → 2AB ΔH = –321 kJ
Bond energy (A2) = 1/2AB
Bond energy (B2) =393 kJ/mol.
What is the numerical value for Bond energy (A2) ?
Question options:
554 kJ/mol
714 kJ/mol
-161 kJ/mol
238 kJ/mol
2. Element A has an electronegativity of 0.8 and element B has an
electronegativity of 3.0. Which statement best describes the bonding in
A3B?
Question options:
The compound is largely ionic with A as the anion.
The AB bond is largely covalent with a δ+ on A.
The compound is largely ionic with A as the cation.
The AB bond is largely covalent with a δ- on A.
3. Which is the longest bond?
Question options:
N-N
N≡N
All three bond lengths should be about the same.
N=N
4. Estimate the heat of combustion for one mole of acetylene:
, CHEM133
Final Exam Study Questions
Lessons 4-7
C2H2(g) + O2(g) → 2CO2(g) + H2O(g)
Bond Bond Energy (kJ/mol)
C≡C 839
C–H 413
O=O 495
C=O 799
O–H 467
Question options:
-1228 kJ
-447 kJ
365 kJ
1228 kJ
447 kJ
5. Which of the following groups contains no ionic compounds?
Question options:
NaH, CaF2, NaNH2
HCN, NO2, Ca(NO3)2
PCl5, LiBr, Zn(OH)2
CH2O, H2S, NH3
KOH, CCl4, SF4
6. In which case is the bond polarity incorrect?
Question options:
δ+Si–Sδ–
δ+H–Fδ–
δ+Mg–Hδ–
δ+Cl–Iδ–
δ+K–Oδ–
7. The electron pair in a C-F bond could be considered
Question options:
closer to C because carbon has a lower electronegativity than fluorine
, CHEM133
Final Exam Study Questions
Lessons 4-7
closer to C because carbon has a larger radius and thus exerts greater
control over the shared electron pair
centrally located directly between the C and F
an inadequate model since the bond is ionic
closer to F because fluorine has a higher electronegativity than
carbon
8. Which of the following bonds would be the most polar without being
considered ionic?
Question options:
N-O
C-O
O-O
Si-O
Mg-O
9. Which one of the following is most likely to be a covalent compound?
Question options:
CaO
Sr(NO3)2
NF3
CsOH
LiF
10. Which bond has the highest bond dissociation energy?
Question options:
All three bonds should have about the same dissociation energy.
N=N
N≡N
N-N
11. Calculate the lattice energy of NaBr(s), given the following
thermochemical equations, where ΔIE and ΔEA are ionization energy and
electron affinity, respectively.
Na(s) → Na(g) ΔHf° = +107 kJ