Mechanism Summary for A-level AQA Chemistry
!
!#
H H H H H H H H
H H
+
C C H C C H H C C H H3C C C CH3 +
H3C C C CH3
H H Br δ+
Br δ+ Br Br H H
:Br - δ- :Br -
Br δ- Br
H H
!
H3C C C CH3
H H H H Br H
+
H3C C C H H3C C C H
!
δ+ H #
"
H -:OSO
2OH H H H H
OSO 2OH
δ- CH3 C C H
H H CH3 C C H
H3C C C H Br H
H :OH-
OSO 2OH
#
H
H H H H H
H3C C CH3 CH3 +
H3C C H C C CH3 H C C CH3
)& $/-&3
O H +
'2/-4)& O H H
:
$/.$
/2
$/.$ H
#
#
H H H H H H
H H
+
H C C H H C C H H C C H
C C
+
H H H H H O H H O
)& $/-&3'2/- O
H H
4)&$/.$ H
!
!
#
"
H H STEP ONE Initiation
δ+ δ- Essential condition: UV light
H3C C Br H3C C OH + :Br -
Br2 2Br
.
-HO:
H H
STEP TWO Propagation
CH3CH3 + Br HBr + CH3CH2
. .
!#
.
CH3CH2 + Br2 CH3CH2Br + Br
.
H H
δ + δ- STEP THREE Termination
H 3C C Br H 3C C CN + :Br - .
CH3CH2 + Br CH3CH2Br
.
-NC:
H H .
CH3CH2 + CH3CH2 CH3CH2CH2CH3
.
!
!#
H H H H H H H H
H H
+
C C H C C H H C C H H3C C C CH3 +
H3C C C CH3
H H Br δ+
Br δ+ Br Br H H
:Br - δ- :Br -
Br δ- Br
H H
!
H3C C C CH3
H H H H Br H
+
H3C C C H H3C C C H
!
δ+ H #
"
H -:OSO
2OH H H H H
OSO 2OH
δ- CH3 C C H
H H CH3 C C H
H3C C C H Br H
H :OH-
OSO 2OH
#
H
H H H H H
H3C C CH3 CH3 +
H3C C H C C CH3 H C C CH3
)& $/-&3
O H +
'2/-4)& O H H
:
$/.$
/2
$/.$ H
#
#
H H H H H H
H H
+
H C C H H C C H H C C H
C C
+
H H H H H O H H O
)& $/-&3'2/- O
H H
4)&$/.$ H
!
!
#
"
H H STEP ONE Initiation
δ+ δ- Essential condition: UV light
H3C C Br H3C C OH + :Br -
Br2 2Br
.
-HO:
H H
STEP TWO Propagation
CH3CH3 + Br HBr + CH3CH2
. .
!#
.
CH3CH2 + Br2 CH3CH2Br + Br
.
H H
δ + δ- STEP THREE Termination
H 3C C Br H 3C C CN + :Br - .
CH3CH2 + Br CH3CH2Br
.
-NC:
H H .
CH3CH2 + CH3CH2 CH3CH2CH2CH3
.