QUESTIONS WITH VERIFIED ANSWERS
PACKAGE
●● equation for enthalpy of a solution
Answer: Hslon = Hsolv + Hsolu + Hmix
Hmix = exothermic
H solv & Hsolu = endothermic
Hsoln = Hlattice + Hhydr
lattice is always positive
hydration is always negative
●● exothermic enthalpy of a solution
Answer: Hsoln < 0
Hmix > Hsolv + Hsolu
●● endothermic enthalpy of a solution
Answer: Hsoln > 0
Hmix < Hsolv + Hsolu
●● Henry's Law
,Answer: S = k*P
●● molality
Answer: mol solute / kg of solvent
●● mole fraction
Answer: mol solute / mol of solute + solvent
●● Freezing point depression
Answer: (FPsolvent - FPsolution) = T = imKf
●● boiling point elevation
Answer: (BPsolution - BPsolvent) = T = imKb
●● relationship between solubility and vapor pressure
Answer: as vapor pressure increases, solubility decreases and vice versa
●● raoult's law
Answer: ΔP = mole fraction solvent & Partial pressure solvent
●● osmotic pressure (pi)
Answer: pi = MRT
, R = 0.0821
T = temperature in kelvin
●● how to solve for Δs, H, G rxn
Answer: ΔSrxn = S product - S reactants
same for G and H, just switch out variables
●● When does entropy increase
Answer: higher temperature
larger volume
more complex molecules
heavier molecules
increases in mols of gas
gas>liquid>solid
more gasses on product side
more product molecules than reactants
●● How to solve for ΔS uni
Answer: ΔSuni = Ssurr + Ssys
●● ΔSuni > 0
Answer: spontaneous