Exam (elaborations) TEST BANK FOR Organic Chemistry 11th Edition by Graham Solomons, Craig Fryhle and Scott Snyder (CHAPTER 16)

Exam (elaborations) TEST BANK FOR Organic Chemistry 11th Edition by Graham Solomons, Craig Fryhle and Scott Snyder (CHAPTER 16) Package Title: Solomons Test Bank Course Title: Solomons 11e Chapter Number: 16 Question type: Multiple Choice 1) What is the correct IUPAC name for the following compound? O a) 2-Methyl-5-heptanone b) 7-Methyl-4-octanone c) 6-Isopropyl-4-octanone d) Isobutyl propyl ketone e) 1,1-Dimethyl-4-heptanone Answer: B Topic: Nomenclature Section: 16.2 Difficulty Level: Easy 2) What is the correct structure for 7-methyl-4-octanone? OOOOIIIIIIIVVO a) I b) II c) III d) IV e) V Answer: D Topic: Nomenclature 1 Section: 16.2 Difficulty Level: Easy 3) What is the correct IUPAC name for the following compound? O a) 5,5-Dimethyl-2-heptanone b) 5-Ethyl-5,5-dimethyl-Methyl-2-octanone c) 5-Ethyl-5-methyl- 2-hexanone d) 5,5-Dimethyl-2-octanone e) 3,3-Dimethyl-6-heptanone Answer: A Topic: Nomenclature Section: 16.2 Difficulty Level: Easy 4) What is the correct structure for 5,5-dimethyl-2-heptanone? IIIIIIIVVOHOOOO a) I b) II c) III d) IV e) V Answer: B Topic: Nomenclature Section: 16.2 Difficulty Level: Easy 2 5) A correct name for the following compound would be which of those below? HO a) 2,5-Dimethyl-6-hexanal b) 2,5-Dimethylhexanal c) 2-Aldehydoisohexane d) 3,5-Dimethylheptanone e) 1-Hydro-2,5-dimethyl-1-hexanone Answer: B Topic: Nomenclature Section: 16.2 Difficulty Level: Easy 6) What is the correct structure for 2,5-dimethylhexanal? IIIIIIIVVHOOOHOHO a) I b) II c) III d) IV e) V Answer: D Topic: Nomenclature Section: 16.2 Difficulty Level: Easy 7) What is the correct IUPAC name for the following compound? 3 O a) 5,5-Dimethyl-2-heptanone b) 5-Ethyl-5,5-dimethyl-Methyl-2-octanone c) 5,5-Dimethylcycloheptanone d) 4,4-Dimethylcycloheptanone e) 3,3-Dimethylcycloheptanone Answer: D Topic: Nomenclature Section: 16.2 Difficulty Level: Medium 8) What is the correct IUPAC name for the following compound? O a) 2,4-dimethyl-2-pentenone b) 2,5-dimethylcyclopenten-3-one c) 2,4-dimethylcyclopent-2-enone d) 3,5-dimethylcyclopent-2-enone e) 2-methyl-5-methylcyclopent-2-enone Answer: C Topic: Nomenclature Section: 16.2 Difficulty Level: Medium 9) What is the correct IUPAC name for the following compound? O 4 a) 1,1,2-Trimethyl-1,3-hexenone b) 1,2-Dimethyl-1,3-hexenone c) 2,3-Dimethyl-1,3-heptenone d) 2,3-Dimethyl-2-hepten-4-one e) 5,6-Dimethyl-5-hepten-4-one Answer: D Topic: Nomenclature Section: 16.2 Difficulty Level: Medium 10) What is the correct structure for 2,3-dimethyl-2-hepten-4-one? OOOOOIIIIIIIVV a) I b) II c) III d) IV e) V Answer: E Topic: Nomenclature Section: 16.2 Difficulty Level: Medium 11) A correct name for C6H5CH2CH2CHO is? a) 3-Benzylpropanone 5 b) 3-Phenylpropanal c) 3-Benzylpropanal d) Nonanone e) Nonanal Answer: B Topic: Nomenclature Section: 16.2 Difficulty Level: Medium 12) What is the correct structure for 3-phenylpropanal? OOOHHOOIIIIIIIVV a) I b) II c) III d) IV e) V Answer: E Topic: Nomenclature Section: 16.2 Difficulty Level: Medium 13) What is the correct structure for 5-hydroxy-2-phenyl-3-hexanone? 6 OHOOHPhPhOHOPhPhOHOPhHOOHIIIIIIIVVO a) I b) II c) III d) IV e) V Answer: C Topic: Nomenclature Section: 16.2 Difficulty Level: Medium 14) Which is the proper name for the structure shown? CHOCH3Cl a) 2-Chloro-5-aldehydotoluene b) 6-Chloro-3-aldehydotoluene c) 2-Methyl-4-aldehydochlorobenzene d) 4-Chloro-3-methylbenzaldehyde e) 4-Methyl-5-chloro-2-benzaldehyde Answer: D Topic: Nomenclature Section: 16.2 Difficulty Level: Medium 15) What is the correct structure for 4-chloro-3-methylbenzaldehyde? 7 HOHOHOHOClClClClHOClIIIIIIIVV a) I b) II c) III d) IV e) V Answer: A Topic: Nomenclature Section: 16.2 Difficulty Level: Medium 16) What is the correct structure for 3-methyl-5-(2,5-dinitrophenyl)pentanal? 8 OHOHOHONO2O2NO2NHOO2NO2NNO2NO2NO2NO2NO2IIIIIIIVV a) I b) II c) III d) IV e) V Answer: B Topic: Nomenclature Section: 16.2 Difficulty Level: Medium 17) What is the correct structure for 3-methyl-5-(4-chlorophenyl)hexanal? 9 HHHHClOClOOClClOClOIIIIIIIVV a) I b) II c) III d) IV e) V Answer: D Topic: Nomenclature Section: 16.2 Difficulty Level: Medium 18) What is the correct structure for 7-bromo-1-octyn-4-one? BrOOBrOBrBrOOBrIIIIIIIVV 10 a) I b) II c) III d) IV e) V Answer: A Topic: Nomenclature Section: 16.2 Difficulty Level: Medium 19) What is the correct IUPAC name for the following compound? OBr a)2-Methyl-2-bromobutanone b)(S)-2-Bromo-2-methylcyclobutanone c)(R)-2-Bromo-2-methylcyclobutanone d) (S)-1-Bromo-1-methyl-2-cyclobutanone e)(R)-1-Bromo-1-methyl-2-cyclobutanone Answer: B Topic: Nomenclature Section: 16.2 Difficulty Level: Hard 20) What is the correct IUPAC name for the following compound? a)2-Bromobutanone b)(S)-2-Bromo-cyclobutanone c)(R)-2-Bromo-cyclobutanone d) (S)-1-Bromo-2-cyclobutanone e)(R)-1-Bromo-2-cyclobutanone Answer:C 11 Topic: Nomenclature Section: 16.2 Difficulty Level: Hard 21) What is the correct IUPAC name for the following compound? OClH a) (S)-3-chloro-1-hexanone b) (S)-1-chloro-3-hexanone c) (R)-3-chlorocyclohexanone d) (S)-3-chlorocyclohexanone e) (S)-1-chloro-3-cyclohexanone Answer: D Topic: Nomenclature Section: 16.2 Difficulty Level: Hard 22) What is the correct IUPAC name for the following compound? a) (S)-3-chloro-1-hexanone b) (S)-1-chloro-3-hexanone c) (R)-3-chlorocyclohexanone d) (S)-3-chlorocyclohexanone e) (S)-1-chloro-3-cyclohexanone Answer:C Topic: Nomenclature Section: 16.2 Difficulty Level: Hard 12 23) What is the correct IUPAC name for the following compound? a) (1S, 4R)-bicyclo[2.2.1]hexan-2-one b) (1S, 4R)-bicyclo[2.1.2]heptan-2-one c) (1S, 4R)-bicyclo[2.2.1]heptan-2-one d) (1R, 4S)-bicyclo[2.1.1]heptan-2-one