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Class notes Applications of quantum mechanics-Solid state

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Engineering Physics notes consisting of-Drawbacks, merits and comparison of quantum free electron theory and classical electron theory. Application of quantum mechanics in solid state. Introduction to Bloch theorem. Explanation of band energy structures in solid states using Kronig and Penney model. Superconductivity and Meissner’s effect.

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UNIT-2 PHYSICS
Applications of Quantum Mechanics -

Solid state




Shreya Prasad

, SUMMARY

→ Classical theory ? Relaxation time
2
thermal velocity
=3km Drift velocity Vd=el
/




heard
R=
F- nerd J=rE
F-
S=£
↳ Mattheis entente :
f- fiefm metal G- R
{
_ -




) (
net impurity


Quantum theory :



KTF E Mtr
k¥p
k=nI
=

Ep Neff net
- __



a
Tomar
probability f-④
eE-Er!lk
=




factor
available
States
n =



¥§mµa "rE
'VE
stale

density
g = Efg)ˢ
Energy density NCE )=gE ) f- (E)-




n-t%E3dtfumivdou.ly
Nooffneeé

VF=j2EmI
Effective
f%¥yE_ =§Ef

man
Ewg=

h-2ci-E.im?-.)--EE.:.7E-oueD
M =




lorenz
1--4--2=-1,1%5
no He Ho
4- ¥ ) ]
-

. -




?⃝

, CLASSICAL ELECTRON THEORY
→ thermal
velocity
=


21mi =

3- KI ( %)
ruax-H-mier-fskm.TT I µ conductivity
nerd
velocity Vd=eE÷ I=neAVd
→ J= E-
Drift F- r
:




classical election
considered
theory
Mobility µ=eIm ¥
→ : =
manual
Boltzmann
theory
↳ Resistivity
:




^





8=10 at T -0k Residual I is present
%
.




9=9,1 Pres



(
-
5- E-
g
r ,

Residual s E
S S E-
ne¥
T→ = - =




impunity
.




g- nerd




Ym
m m
!
=




net net nets litres impurities)
§ is dueto


&
'

I Eres II
=




B-
* CEFT DRAWBACKS :




1. Temperature dependence of S :
C- Vs s)




=÷a
f =
M "
not
s=
mn֖
S m
]3kyB
=




helps
3kBh =




need
safe


But in 8×7
reality
i.
,

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