erythromycin quilt ,
-
got chlorinated surfeit -
0,11
carboxylic acid =
R -
c=0 acyl chlorides = R -
[ = OH esters -_ R - É=O -
R
-
www.greqivofifuerof-vgttrrxyfiro-gtittiptyeyofd _qwfqkMvof8
strong acid +
base → salt + H20
a
carboxylic acid +
sodium metal carboxylic acid > phenol > alcohol
,
0
off + H2 ' 9)
strength Of acidity
CF0H
Na R -
-
Nat
-
+ I. But HC1 is e- strongest acid
R -
a
carboxylic acid + strong base NA0H
R -
c + Na -
OH - R - + H20 (1)
10 Nat
-
µ
.
carboxylic acid + weak base N9H CO3
°
r - + NAHCO } -
R - [ - o
-
Nat
+
H20 1II
+
CO2 (g)
-
OH
'
phenol +
sodium vfT9I N9 .
9100401 +
sodium metal N9
-0 Not H≥
_
OH N9
-
11219 )
-
-
OH + Na - + R -
+ - R -
O Na +
.
phenol +
sodium base NaOH '
alcohol -1 Sodium base NA0H
NA0H O Nat H20 NA0H-0NO REACTION
-
-
OH + -0 -
+ ie ) R -
OH +
•
phenol + weak base .
alcohol + weak base N9H CO3
-
OH + NAHCO } -0 NO REACTION R -
OH + NAMCO } - NO REACTION
extermination virtualisation with CO0H Y-qvyfthyfof.tt
☆ .
ESTER NAMING
from CO0H ethayoqte
£[
=
R -
☐µ
+
µ
/
° -
R
④ +
from alcohol
H
=
-
OH
methyl
: alkyl carboxylate __ methyl emanate
electrophilic
Carboy
R¥°
from CO0H = ethayoqte
+
/
0 -
¥0 + H -
OH :
phenyl carboxylate __ e-14940917
" " " ✗ 9 ""
+
OH µ
from alcohol = cyclone✗ 9441
•
ESTER FORMATION -
esterification / condensation
→ CO0H +
alcohol
4° H
' 0€ + H -
OH
R -
c- OH +
R -
O R -
o -
R
→ CO0H + phenol
R -
¥-0M +
µ
-0
-
É r
-
µ
+ H -
OH
-0941 Chloride +
alcohol
i
R -
c- ce
+
µ _ oÉ° R - Eto -
r
+ H -
ce
→
941 Chloride + phenol
i or o
+ H -
ce
ce
-
+ o
- -
r -
c- µ -
-
got chlorinated surfeit -
0,11
carboxylic acid =
R -
c=0 acyl chlorides = R -
[ = OH esters -_ R - É=O -
R
-
www.greqivofifuerof-vgttrrxyfiro-gtittiptyeyofd _qwfqkMvof8
strong acid +
base → salt + H20
a
carboxylic acid +
sodium metal carboxylic acid > phenol > alcohol
,
0
off + H2 ' 9)
strength Of acidity
CF0H
Na R -
-
Nat
-
+ I. But HC1 is e- strongest acid
R -
a
carboxylic acid + strong base NA0H
R -
c + Na -
OH - R - + H20 (1)
10 Nat
-
µ
.
carboxylic acid + weak base N9H CO3
°
r - + NAHCO } -
R - [ - o
-
Nat
+
H20 1II
+
CO2 (g)
-
OH
'
phenol +
sodium vfT9I N9 .
9100401 +
sodium metal N9
-0 Not H≥
_
OH N9
-
11219 )
-
-
OH + Na - + R -
+ - R -
O Na +
.
phenol +
sodium base NaOH '
alcohol -1 Sodium base NA0H
NA0H O Nat H20 NA0H-0NO REACTION
-
-
OH + -0 -
+ ie ) R -
OH +
•
phenol + weak base .
alcohol + weak base N9H CO3
-
OH + NAHCO } -0 NO REACTION R -
OH + NAMCO } - NO REACTION
extermination virtualisation with CO0H Y-qvyfthyfof.tt
☆ .
ESTER NAMING
from CO0H ethayoqte
£[
=
R -
☐µ
+
µ
/
° -
R
④ +
from alcohol
H
=
-
OH
methyl
: alkyl carboxylate __ methyl emanate
electrophilic
Carboy
R¥°
from CO0H = ethayoqte
+
/
0 -
¥0 + H -
OH :
phenyl carboxylate __ e-14940917
" " " ✗ 9 ""
+
OH µ
from alcohol = cyclone✗ 9441
•
ESTER FORMATION -
esterification / condensation
→ CO0H +
alcohol
4° H
' 0€ + H -
OH
R -
c- OH +
R -
O R -
o -
R
→ CO0H + phenol
R -
¥-0M +
µ
-0
-
É r
-
µ
+ H -
OH
-0941 Chloride +
alcohol
i
R -
c- ce
+
µ _ oÉ° R - Eto -
r
+ H -
ce
→
941 Chloride + phenol
i or o
+ H -
ce
ce
-
+ o
- -
r -
c- µ -
