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Summary Aldehydes and ketones

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what are the different reactions and tests ketone and aldehydes are involved in? I've got just what you need!! here's a handwritten summary, with working examples and solutions.

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Truthful without -




carbonyl groyps

i
R - _
µ
=
aldehyde R -
C -
R =
ketone

4) oxidation adding OT0H when there's f) oxidation because there isn't 911-1099901-0

9119-1190491-0 the hydrophilic


cgrboy-qfqetyyofeoxirofqfiowfo-cqfkrxyf.ro -


quilt Whiff H+ / K My 04 oyH+ / K2 C22 07 of H+ / NQ2W 07

chemical test →
pyrplegcidickmn04soly-ioywillchqyge-ocoloyrletrwhe.in by -19491 is oxidised into by-19401-099'd
a




returning
-

aldehyde reduction -10 primary alcohol .
Ketone reduction -10 secondary alcohol

USING H2 / ptORLiAÑ4↑ÉÑrL USING H2 1PT OR LiAlH4 / ether

0,4 0,11
H - -

CH2 -
CH3
o H -
CH -
CH2 -

CH3 - ¥ -

CH2 -

CH3
H2-1PT -
CH -
CH2 -

CH3



trotters test
.
silver mirror test

→ functional group test to detect presence of aldehyde R -
É -
H

-0 4) reaction =
Ag formed black precipitate
=
aldehyde present
+

redox reaction using [A9 1NH } / 2)
'





" " + " " "
\o/ [ A9 1NH } / 2) Rig / A9 1SI
"
C
' "

-1^9%121 no reaction
BUT IF IT WERE
+
-

: : -

silver
KETONE . . .
I
Mirror
91¥ ×yÉ
'




tellings test
.
chemical test -
to test for presence of aldehyde
→ 1+1 reaction =
hedppt formed

" "
feyiiygssoly-ioy-KY.tt
' " "
'
c
+ " 201st " '
c
BUT IF / 1- WERE fehling.sk/h-i0h-yoreqc-ion
É 1 -


car
:[ mate
KETONE . . .
y


2
,
4 -
b N PH test
chemical test to test for presence of carbonyl compounds
'
-




→ It) reaction = Yellow toned PPTformed


NN
N°2
2,4 dini-ropH.my / hydrazine
a
- :

NH2


'

with aldehyde

""


t↑,%=K;
R H ^"


I:[ ← 1-
-
c- + ""
*

,


with ketone
'




N°2 ^"
NO2Y,
kick
:
+
- -
NII -
↑¥N=K£ + H20

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Written in
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