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Summary Molecular orbital theory

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A well explained summary of molecular orbital theory covered in the first term of 1st year Durham university. This includes adding and subtracting atomic orbitals to form molecular orbitals, and molecular orbital diagrams. All relevant definitions are included, and all relevant diagrams are included.

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Institution
Durham University (DUT)
Course
Core Chemistry 1 (CHEM1078)

Content preview

NO
theory

Year I

, Valerie bond -
localised electrons
bonding atoms together

Molecular orbital theory -
delocalised
electrons across
H atom Is
'

the active model
"
r 4am

✗
angular
wave

function

, molecule He
miest B
1s

Ihsdosenator Al
Imogenar
H
A

⑪ ,
for apart

Bring (fose
together
have A ware
waves

side interact
t
for both <add and substract
(reflection
f Radial wave functions considered

H closer together
H
A Bring and the interfere B
↓ I




I~

MA radius ↑Hs) radius
Molecular orbital Bonding (as high density in mild be
anucei)
Orbital New
constructive warefraction
-
4He
-

~
2

L
↓




I
t




I
-




Linear combination
atomic orbitals
enhanced electron densit
*



(LCAO)
between two the nuclei (Hin, ins
and
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Institution
Durham University (DUT)
Study
Unknown
Course
Core Chemistry 1 (CHEM1078)
All documents for this subject (9)

Document information

Uploaded on
May 28, 2023
Number of pages
25
Written in
2022/2023
Type
SUMMARY

Subjects

  • molecular orbital theory
  • bonding orbitals
  • anti bonding orbitals
  • homo
  • lumo
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