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Summary Atomic structure CHEM1078

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Detailed summary of all topics covered in the atomic structure sub module. Including angular wave functions and radial wave functions, and all relevant equations and definitions.

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Course

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Core Chemistry 1




Year 1
Atomic structure
1st Year

, 3/10/22

Lecture 1 structure and boarding
and 2
QvartvmTheory_

( Hoo -



1925 ) treated electron like a
particle .
c- Easier to understand
Atoms -
electrons in orbit
.
Bohr Model → doesn't obey classical
mechanics

Doesn't explain enperi mental observations




(1925 -
Now ) Electron as a wave

Atoms -
electrons in orbitals
Explains everything
Harder to viii. Mile

Quantum → small things → certain amount of

Restrict
have
IÑññ,
certain restricted
to

values .




Quark led → only certain values
restrilkd
-


Money -

to multiples of an integer cake

250 p
[ IT
Quantum have my lover
→ how man mumbles You
number number




0i42,3_..
All Quantum
numb


1-2 -
'
, -2



?⃝

, Bohrmodet
73
^
n= ' -
-
. -
. _




circular orbit
.



_ -
/
-
momentum
angular
\

y ,
/
"
↓ means
can
only have
" ' ,
certain vanes
certain orbitals
"

only
'
'
e-
mr={
,
e- •• • a. + y ,
allowed
I r r ↓
_
-




does NOT obey
b- planks
-
"
this constant
mechanics
'
- ✓ classical 2
- - -
created
bear"
when Intra moves from one orbital using
d- M
to another energy is released as light
,

Bohr plucked
Clacsical Mechanics world mean
misono
min
- r

g
electron becomes closer and closer to air

nucleus and therefore atoms wouldn't
,




exist .
This il why Bohr model is


flared
22 AhYf%?: name


m÷ (kind ¥
= '
me
¥◦rt Energy =
-




Ex -
1-

E. h2
N2
r=
n
' radius a n2

¥ , where n = 1,2, ]
- c. . . . 0


Bohr radius =/ do when n=l
'

6m
%
radius 0.52917×10
-




=


Radio H atom according to Bohr
BOHR RADIUS thmobure 10
'
in
_




radio
?⃝ ?⃝

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Number of pages
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Written in
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Type
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