,::r---
CLASSIFYINf AUOHOU ,h(t1'o. f':j
PHVSICIU. PltOPf~rlES
3•
•Con torrn h~drogen bOYlctS
.', i1'c.rcos.ed !.olu.bilit~(in pol or
!· _ Iii!
0
Solventt)
\
0
H-
pnmo~ •
1-\
(.-01-\
. '1i!
2 ° s.e co,, clofj
~,
I
H-C-C-C-14
1-\ ...,
1 I
H 3 C-
-# I
C- CH3
:. inc.reos.til b.p. (dc.creo':.e.d vo\o.ti1 I I I \ I
1-1 oH 1:-1 ot-1
• As choin u.ngH, if1c.r<2O':.el ths.. il\p1.1.1.11c.t 1-1
ffOP(\l\ ·1- 0 L 1-M tt h~ Ip rop o. l'\·1-0 l
Of tl'lt -OH group b~cow s rtl0-n v- t1y ~tno.nol
Sl\'lo. ll tr 30 tl'\t d1fftrenusc.omy,a.rtol ca rbon l,\IHHthect to t
o. tta~ch..l.ci to 3o+her
1othtr co.(bol'lS
w1rn atllO..~S d.Q.lr~O.HJ {prcpi?rn"eJ buoi'\1..2. o.ttatcned carbons.
~or~ \IIU thOH Ofan (l\lC.Qne) '~,o~t~
~hqdroq~n
wo~r moLte,u,u.:bo"~ bUwUil pr11~0.n-1-ol ancl o..
,-r HI'
<OrtJOn .
t ~etphon°methMc!
11
r I'
Cl-\ sCri 2 (H t --o.r.:----H-(J: ..i,
m_tthOMll)ClllOCln
,mportc,nl chlr,\l(Ql
./; . . • fUG\rloc,it It-con ht
homo109ous se.n es e 0. f-O.rr'll 1y Of_COM!lOUl\llJ ,Nlth I-ht (01\VtfrL~ Wo
so.mt f-uncn·ono.l group o.!'ld siMtlo.r chemico.1 pr119Utie; 101yroer.s, ,e11_
101J, .
v-.1nca suueui"~ Mtl"(lb~rJ c:tilftr by i-ht o.(iclff)Ol'l 0fO. -cl-1 1- so,vtnis_,
o.<1.nu,vtl.nl"l~non.
<311lUf- etno.nol i, ~,;• ~td
~w•
to
·I\~ cho.inien9!l, '""u,u
• 1,.p .il\<rt<>HI d.wlO ~""~"
. . ' '"'"gtrl lvlort londoo u,
1t.,01vtntond
~, f-tt<.Uto pnme1ru
. 14.!td as
f1Jrtu. Mo ~, (,ll,V9'J ,J rtq,,1,t irtd -t• 1,, rto IC t-h-tll <4d.d.lf'I onoL/SHon9e.r- Londo n 1-4,c.R... ,......._ _ _,....-.~-"'o.fU j d
. pro.p~nc - J,2,J - 1ri ol 1·r mor~Jo/vt<lht:1,. ,ropoti -1- IL ho-tc c:H.U t.tfttr~Q, ' A
ot< gro.-PJ att ol1:htci"~"' !./"'"'~ ,.,a,hotf.rog,n loond F/fdwt<d w i ,h wot<r moue 1
ton . OlS. ' A o.l cohO II C
fH rtoter "" J o/Ubil(uf'
1more hyd•••nd-,om<Ld i,e;;,.,u.,, a ,,..,<Lct,<l.Q. ondw• ~" n"-3.
~.ACT\ON' 0, ALCOtiOLS~
,)cclYlbU.'!l.'tt_9'l ·. l)fesen02. of Oat-o'Nl rno..lC!I.S. l>Et\Yt>ltA'"Ot,.l- eli rnin ah on react-ion . t limino.t10Y1 removal of Cl sYY1C\II
wJlt-ftff'i'mancc. O..lCOhols. burn mor<2 ~ho.n H ... H mol.HU.U from a targtr mou.c_l,I.LJ...
lllP04-
qt:,c,~tle
Jorge 'iP"""'Y of tnt<}i~ n"h.~ 10~J,,o,,')l/;'f~. More. hW" · . Hz(- C.- C-OH
1 I I
H3C.-C=-C
/ ~,
t H20
1 1 ref LUX ' H
·2)oxido:hon·, k.z. Cr2.O-:i /N OzCr20-. 1-1
Propo.r1-1 -o L
H PYop me
Cr 2 o.,'2·
.,-
d .d
Tll \.lc.l-
} (,'~• o
1\
TG
Sf
• ~n R- - c - H IUl'STIMION ~\Ttl MvoaOG-tN KAU OIS
rJ
t
or().r,~ . 1~hucl-t
ci---rornt.ttiOO c-hrom,1.un ,on. °'ll' , 1-1 1-1 ';i rt 0
Primorg Gitt ho I.S: tl• ',..,,Y"'- 2) caro()J(;,ic ""'" 1-1 H3 ( .. (. - C- 01-1 +- H l - C-C,-c.A. t-H1
11 y haH~ 3 I I
,..' 'rl 2 0
C O ' . I , I
<-i
1
,;
1 [] ~ ) 1-1- c.-C,1-1 .- H r-1 ~od iun, ho.Ii~ H H '> l\ 0,loo. l\C.O.OeS
0
w
l-1 - ( - ( - 0 t-1 Ht 304 , /JfP{)On- 1-oL -t- su.lfu.ri c. acid c/1/0r opropone form~d .
1 I t . d . k.L H O h~Gtt:ed 1.,1.ncU-r
H H G<id1s,n.9
tt\1(10 ~
. "
,A ~-C-OH '4 re+ /M.x.
"'
IH110.,nol
.,.. H
~9._....t
i pre<enlscrn
fv,r,1'1,t(•Q.ct~oo -
..,., 1t-hox1d1'>1n.9 0 9'l"t,
-
H O
,corbO~~l• C.
tt- o.CJ,d SL'bl n·ru. hon, tl\'1 CltOm or 910\.\PCf-£\IOM.l ilreplatto b\l a ,hffll rnt
, 1 )( Cr,01 ' 11 1 -'- "--1 0 Morn or group of MCIY!J
H- (-( - Oli \-1[]
O /l-l1SO~
~ H - C-
, C- 0 ~ '1
1
H ~I . H . ·ct
""°"
iathO.nOL ~~ctinW.lll~ etnonO\COtl 0
Q/\1,c\CeC\II (ll(Ol'\01 II " ,
d rto,y .,co1to11: G>t\ d.\S~cl.. ~
ii
,..-)
, 1- o
~13,t- l-c.H3 t (o) H3C ·C Cti_i 1 12
I H1 4
OH ref:u.i.x propo.non
,J&Cln-i-ol
ff!ll''0'1 tdu/lots: do NOT uncle..rgo -'I the 1ucid i ~iot
4 no Ho tom~ att o.+thttl ox,d.anon reach'onJ. d_chrol'(\e1t{(1v)
c- ~rt
-<O H1~_ gf!lU./!• _ r(/M1ns or an.9 t.
CLASSIFYINf AUOHOU ,h(t1'o. f':j
PHVSICIU. PltOPf~rlES
3•
•Con torrn h~drogen bOYlctS
.', i1'c.rcos.ed !.olu.bilit~(in pol or
!· _ Iii!
0
Solventt)
\
0
H-
pnmo~ •
1-\
(.-01-\
. '1i!
2 ° s.e co,, clofj
~,
I
H-C-C-C-14
1-\ ...,
1 I
H 3 C-
-# I
C- CH3
:. inc.reos.til b.p. (dc.creo':.e.d vo\o.ti1 I I I \ I
1-1 oH 1:-1 ot-1
• As choin u.ngH, if1c.r<2O':.el ths.. il\p1.1.1.11c.t 1-1
ffOP(\l\ ·1- 0 L 1-M tt h~ Ip rop o. l'\·1-0 l
Of tl'lt -OH group b~cow s rtl0-n v- t1y ~tno.nol
Sl\'lo. ll tr 30 tl'\t d1fftrenusc.omy,a.rtol ca rbon l,\IHHthect to t
o. tta~ch..l.ci to 3o+her
1othtr co.(bol'lS
w1rn atllO..~S d.Q.lr~O.HJ {prcpi?rn"eJ buoi'\1..2. o.ttatcned carbons.
~or~ \IIU thOH Ofan (l\lC.Qne) '~,o~t~
~hqdroq~n
wo~r moLte,u,u.:bo"~ bUwUil pr11~0.n-1-ol ancl o..
,-r HI'
<OrtJOn .
t ~etphon°methMc!
11
r I'
Cl-\ sCri 2 (H t --o.r.:----H-(J: ..i,
m_tthOMll)ClllOCln
,mportc,nl chlr,\l(Ql
./; . . • fUG\rloc,it It-con ht
homo109ous se.n es e 0. f-O.rr'll 1y Of_COM!lOUl\llJ ,Nlth I-ht (01\VtfrL~ Wo
so.mt f-uncn·ono.l group o.!'ld siMtlo.r chemico.1 pr119Utie; 101yroer.s, ,e11_
101J, .
v-.1nca suueui"~ Mtl"(lb~rJ c:tilftr by i-ht o.(iclff)Ol'l 0fO. -cl-1 1- so,vtnis_,
o.<1.nu,vtl.nl"l~non.
<311lUf- etno.nol i, ~,;• ~td
~w•
to
·I\~ cho.inien9!l, '""u,u
• 1,.p .il\<rt<>HI d.wlO ~""~"
. . ' '"'"gtrl lvlort londoo u,
1t.,01vtntond
~, f-tt<.Uto pnme1ru
. 14.!td as
f1Jrtu. Mo ~, (,ll,V9'J ,J rtq,,1,t irtd -t• 1,, rto IC t-h-tll <4d.d.lf'I onoL/SHon9e.r- Londo n 1-4,c.R... ,......._ _ _,....-.~-"'o.fU j d
. pro.p~nc - J,2,J - 1ri ol 1·r mor~Jo/vt<lht:1,. ,ropoti -1- IL ho-tc c:H.U t.tfttr~Q, ' A
ot< gro.-PJ att ol1:htci"~"' !./"'"'~ ,.,a,hotf.rog,n loond F/fdwt<d w i ,h wot<r moue 1
ton . OlS. ' A o.l cohO II C
fH rtoter "" J o/Ubil(uf'
1more hyd•••nd-,om<Ld i,e;;,.,u.,, a ,,..,<Lct,<l.Q. ondw• ~" n"-3.
~.ACT\ON' 0, ALCOtiOLS~
,)cclYlbU.'!l.'tt_9'l ·. l)fesen02. of Oat-o'Nl rno..lC!I.S. l>Et\Yt>ltA'"Ot,.l- eli rnin ah on react-ion . t limino.t10Y1 removal of Cl sYY1C\II
wJlt-ftff'i'mancc. O..lCOhols. burn mor<2 ~ho.n H ... H mol.HU.U from a targtr mou.c_l,I.LJ...
lllP04-
qt:,c,~tle
Jorge 'iP"""'Y of tnt<}i~ n"h.~ 10~J,,o,,')l/;'f~. More. hW" · . Hz(- C.- C-OH
1 I I
H3C.-C=-C
/ ~,
t H20
1 1 ref LUX ' H
·2)oxido:hon·, k.z. Cr2.O-:i /N OzCr20-. 1-1
Propo.r1-1 -o L
H PYop me
Cr 2 o.,'2·
.,-
d .d
Tll \.lc.l-
} (,'~• o
1\
TG
Sf
• ~n R- - c - H IUl'STIMION ~\Ttl MvoaOG-tN KAU OIS
rJ
t
or().r,~ . 1~hucl-t
ci---rornt.ttiOO c-hrom,1.un ,on. °'ll' , 1-1 1-1 ';i rt 0
Primorg Gitt ho I.S: tl• ',..,,Y"'- 2) caro()J(;,ic ""'" 1-1 H3 ( .. (. - C- 01-1 +- H l - C-C,-c.A. t-H1
11 y haH~ 3 I I
,..' 'rl 2 0
C O ' . I , I
<-i
1
,;
1 [] ~ ) 1-1- c.-C,1-1 .- H r-1 ~od iun, ho.Ii~ H H '> l\ 0,loo. l\C.O.OeS
0
w
l-1 - ( - ( - 0 t-1 Ht 304 , /JfP{)On- 1-oL -t- su.lfu.ri c. acid c/1/0r opropone form~d .
1 I t . d . k.L H O h~Gtt:ed 1.,1.ncU-r
H H G<id1s,n.9
tt\1(10 ~
. "
,A ~-C-OH '4 re+ /M.x.
"'
IH110.,nol
.,.. H
~9._....t
i pre<enlscrn
fv,r,1'1,t(•Q.ct~oo -
..,., 1t-hox1d1'>1n.9 0 9'l"t,
-
H O
,corbO~~l• C.
tt- o.CJ,d SL'bl n·ru. hon, tl\'1 CltOm or 910\.\PCf-£\IOM.l ilreplatto b\l a ,hffll rnt
, 1 )( Cr,01 ' 11 1 -'- "--1 0 Morn or group of MCIY!J
H- (-( - Oli \-1[]
O /l-l1SO~
~ H - C-
, C- 0 ~ '1
1
H ~I . H . ·ct
""°"
iathO.nOL ~~ctinW.lll~ etnonO\COtl 0
Q/\1,c\CeC\II (ll(Ol'\01 II " ,
d rto,y .,co1to11: G>t\ d.\S~cl.. ~
ii
,..-)
, 1- o
~13,t- l-c.H3 t (o) H3C ·C Cti_i 1 12
I H1 4
OH ref:u.i.x propo.non
,J&Cln-i-ol
ff!ll''0'1 tdu/lots: do NOT uncle..rgo -'I the 1ucid i ~iot
4 no Ho tom~ att o.+thttl ox,d.anon reach'onJ. d_chrol'(\e1t{(1v)
c- ~rt
-<O H1~_ gf!lU./!• _ r(/M1ns or an.9 t.
