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OCR AS Level Chemistry Module 3 Periodic Table and Energy

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This is the second theory module from the OCR AS Level chemistry course.

Instelling
Vak

Voorbeeld van de inhoud

PERIODIC TABLE
AND ENERGY
The Periodic Table
Groups, Periods and Blocks
The periodic table a l l te
hle
e m e n ts by proton from lowest to
arranges
number
highest.
·
Periods
↳ A in the
r ow
periodic table.
↳All elements
t h e i r valence electron in the
with same shell
go
in the same
period.

·
Groups
↳ A in the
c olumn periodic table.

↳Elements in the
group have
same their electrons in similar orbitals

↳ Often have similar properties.
↳Have the same amount of electrons in their o u te r shell.



·
Blocks
↳ The two most left columns make block.
the
up


↳ All the elements in this block have their valence electrons in sorbitals.

Helium

is too in this block.

↳ The the p block.
six
rightmostcolumns make up
↳ All the elements in this block have
partially filled
a
p sub-shell.
↳ d Block lies betweenthe sand
p block.
↳Elements in a block a sub-shell.
have
partially filled
a


↳ The f block is detached
along t h e bottom of the
periodic table.

↳ Elements f block have filled of sub-shell.
in the a
partially


Ionisation Energy
Ionisation energy is the
energy required
to re m ove one mole of
e lectrons
from mole of ions.
one
gaseous atoms or




Xigter) standtesterent
First Ionisation
Energy: Xig -> Xg+e-
Second Ionisation
Energy: Xyl-Xg+e= &




Third Ionisation Energy. Xig
->

,Factors Affecting
Ionisation Energy
·
Distance from t h e nucleus

↳Electrostatic attraction decreases the further electrons a re from nucleus.

↳ Less
energy is needed to re m ove electrons which a re further
away.
↳Therefore as distance increases, ionisation decreases.
energy

Nuclear
charge
·




↳ The the number of
greater protons in the nucleus, the
greater the attraction

of the electrons the
to nucleus.

↳ More is needed remove the electron.
energy
to



Therefore, ionisation
energy is
greater.

·

Shielding
↳The the number of
e lec trons between the
greater nucleus and outer
the electrons,
the lower the effectiveness of
nuclear
charge.
↳Positive electrons
charge that
gets elec trons is
to reduced bythe in between.

↳The the number of ionisation
greater electrons, the lower the
energy.



Ionisation Energy Graph of Sodium
·

The graph shows the trend i n successive


ionisation of sodium. This evidence
energies
for the structure of an atom.




·

Ionisation energy increases with proximityto
the nucleus.


The ionisation
1
n= shell will have a
higher
than the 2 shell.
energy n
=




↳ The 2
n= shell will have a
higher ionisation

energy than the n 3 shell
=




Trends in Ionisation
·
Down a
group
First

ionisation energies decrease.

This is because the atomic radius increases.


Electron is further away from nucleus so
experiences less attraction.

↳ There a re also m o re electrons between the nucleus and the outer electrons.

↳ Outer electrons experience m o re
shielding therefore do not
getthe full attraction.



Across
·
a
period
↳First
ionisation
energy increases.
↳ Atomic radius decreases. Proton number increases electrons a re attracted
across a
period so m o re


to the nucleus.

↳ The electron is closer t h e nucleus attraction.
to so
experiences greater
Nuclear

charge increases across a
period.

, Metallic Bonding and Structure
Metals bond in a different way
to non-metals.



·
Seaoffree electrons
↳ In a metal, the valence electrons delocolise, an d can m ove around the

entire metal.

↳ Metalic sec off ree electrons
bonding is viewed as a
surrounding positive
you cores.

↳The
positive ion core s a re attracted to the free electrons.



·
Electrical conductivity
↳Metals a re
good
electrical conductors because the free electrons can


m ove a n d cur rent.
carry

They a re called
charge car riers.




Melting
·

point
↳Related to the
groupof
the metocl.


Ag roup
2 metal will donate two electrons to the sea of electrons.
↳Positive ion
charge.
h e re 2+
c o re s
carry a


The 2+ ion
stronger attraction to the free electrons.
has a




Melting point is higher.



E.g. Sodium melts a t 98°, Magnesium melts a t 650°C.

Structure ofSolid State Metorls

Metals in a solid state can be defined
by atoms
arranged in rows and held
together through
the principles of metallic
bonding.
·
Metolic lattices
↳ All metals, when solid, their
display atoms in a
giant metallic lattice.
↳Atoms a re
arranged in
regular rows, held in place through electrostatic attraction

between the positive metal ions and their delocolised electrons.

↳ Rows s
able t ol i d e ove r each to bend and be
a re
other, giving metals the ability
beaten into shape (malleable).



Melting and
boiling points
·




↳Metals have a
high level ofa ttrac tion between the metal ions and the electrons.

↳ This they
means, require a lot of
energy
to be
separated and therefore
high melting
and
boiling points.
↳Metals with delocolised electrons tend
m o re to have
higher melting and
boiling points.

·
Electrical conductivity
↳Metals a re
good
electrical conductors because the free electrons can


m ove a n d cur rent.
carry

They a re called
charge car riers.




Strength ofattraction
·




↳ There is the
a
strong attraction between positive metallions and
negative electrons.
↳The easily.
strength of these attractions means metals do not dissolve

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Geüpload op
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Geschreven in
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