Unit 26 – P5, M5 + D5 – Applied Science
P5 – explain corrosion tendency in terms of standard reducton potentall
M5 – calculate the EMF of electrochemical cells using standard reducton potentals from
oxidaton/reducton half euuatonsl
D5 – Analyse the extent to which standard reducton potentals may predict the extent of
corrosion in an industrial contextl
The standard reductin pitental is the tendency fir the reductin if chemicals which is usually
measured in vilts at standard cinditinss t wiuld depend in the mire pisitve is the pitental the
higher is the chance that it wiuld be reduceds t has been placed inti a categiry which is called the
standard cell pitental ir it ciuld alsi be called standard electride pitentals The standard cell
pitental is simething which is the pitental diference between the cathide and anides The
standard cinditins at which the standard pitentals are measured are at 298K, 1 atm and these are
carried iut in 1M silutinss The way in which the standard reductin pitentals are represented is
by reductin half reactinss An example if the standard reductin pitental half reactin ciuld be
seen beliw;
A – element
C – charge if the element
AC++Ce−→A
Cipper’s standard reductin pitental if Eo=+0.340V) fir the reactin can be seen beliw;
Cu2++2e−→Cu
There are alsi standard ixidatin pitentals which is very similar ti the standard reductin
pitentalss The tendency if the substances wiuld be ixidised at the standard cinditins (at 298K, 1
atm and these are carried iut in 1M silutinsss
The standard ixidatin pitental under standard cinditinss
A(s)→Ac++Ce−
The Cipper’s standard ixidatin pitentals
Cu(s)→Cu2++2e−
Eo0(SOP)=−0.34V
The standard ixidatin pitental and the standard reductin pitental tend ti be diferent chargess
There is certain relatin between them;
Eo0(SRP)=−Eo0(SOP)
The standard reductin pitentals can be determined using experimentss The experiment which can
be dine in irder ti measure it is the standard hydrigen electrides A diagram if the standard
hydrigen electrides
, Unit 26 – P5, M5 + D5 – Applied Science
The hydrigen tends ti have the reductin and ixidatin pitentals if 0s When the experiment is
perfirmed, the way in which the ixidatin pitental and the reductin pitental is measured is by
the diference in the pitental frim hydrigens The way in which this is dine by using the galvanic
cells in ine if the sides and the ither side wiuld have an unkniwn chemical being presents A
viltmeter wiuld then be used in irder ti fnd the pitental diference frim the hydrigens When the
experiment is being carried iut the unkniwn chemical wiuld becime reduced and the hydrigen
wiuld becime ixidiseds Hiwever, if the standard ixidatin pitental is being identfed, the
unkniwn chemical wiuld becime ixidised and the hydrigen wiuld becime reduceds The diagram
beliw indicated the standard reductin pitental and hiw it is usually determineds
P5 – explain corrosion tendency in terms of standard reducton potentall
M5 – calculate the EMF of electrochemical cells using standard reducton potentals from
oxidaton/reducton half euuatonsl
D5 – Analyse the extent to which standard reducton potentals may predict the extent of
corrosion in an industrial contextl
The standard reductin pitental is the tendency fir the reductin if chemicals which is usually
measured in vilts at standard cinditinss t wiuld depend in the mire pisitve is the pitental the
higher is the chance that it wiuld be reduceds t has been placed inti a categiry which is called the
standard cell pitental ir it ciuld alsi be called standard electride pitentals The standard cell
pitental is simething which is the pitental diference between the cathide and anides The
standard cinditins at which the standard pitentals are measured are at 298K, 1 atm and these are
carried iut in 1M silutinss The way in which the standard reductin pitentals are represented is
by reductin half reactinss An example if the standard reductin pitental half reactin ciuld be
seen beliw;
A – element
C – charge if the element
AC++Ce−→A
Cipper’s standard reductin pitental if Eo=+0.340V) fir the reactin can be seen beliw;
Cu2++2e−→Cu
There are alsi standard ixidatin pitentals which is very similar ti the standard reductin
pitentalss The tendency if the substances wiuld be ixidised at the standard cinditins (at 298K, 1
atm and these are carried iut in 1M silutinsss
The standard ixidatin pitental under standard cinditinss
A(s)→Ac++Ce−
The Cipper’s standard ixidatin pitentals
Cu(s)→Cu2++2e−
Eo0(SOP)=−0.34V
The standard ixidatin pitental and the standard reductin pitental tend ti be diferent chargess
There is certain relatin between them;
Eo0(SRP)=−Eo0(SOP)
The standard reductin pitentals can be determined using experimentss The experiment which can
be dine in irder ti measure it is the standard hydrigen electrides A diagram if the standard
hydrigen electrides
, Unit 26 – P5, M5 + D5 – Applied Science
The hydrigen tends ti have the reductin and ixidatin pitentals if 0s When the experiment is
perfirmed, the way in which the ixidatin pitental and the reductin pitental is measured is by
the diference in the pitental frim hydrigens The way in which this is dine by using the galvanic
cells in ine if the sides and the ither side wiuld have an unkniwn chemical being presents A
viltmeter wiuld then be used in irder ti fnd the pitental diference frim the hydrigens When the
experiment is being carried iut the unkniwn chemical wiuld becime reduced and the hydrigen
wiuld becime ixidiseds Hiwever, if the standard ixidatin pitental is being identfed, the
unkniwn chemical wiuld becime ixidised and the hydrigen wiuld becime reduceds The diagram
beliw indicated the standard reductin pitental and hiw it is usually determineds
