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Chapter 13_ NMR Spectroscopy.

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Chapter 13_ NMR Spectroscopy.

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Chapter 13: NMR Spectroscopy
NMR is the most powerful tool available for
organic structure determination


NMR spectroscopy uses
radio waves

number of signal means
number of chemically unique H's in the molecule


chemical shift
the types of H's that are present


spin-spin splitting
the H's proximity to each other


what is a proton deshielded by?
the presence of a more electronegative atom (e.g oxygen and nitrogen)


the number of signals shows
how many different kinds of protons are present


the location of the signals shows how
shieled or deshieled is the proton


signal splitting shows
number of protons on adjacent atoms


downfield
movement toward the left in an NMR spectrum


upfield
Movement to the right in an NMR spectrum


the chemical shift of H depends on

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