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Atkins' PHYSICAL CHEMISTRY

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BRIEF CONTENTS PROLOGUE FOCUS 1 The properties of gases FOCUS 2 The First law FOCUS 3 The second and third laws FOCUS 4 Physical transformations of pure substances FOCUS 5 Simple mixtures FOCUS 6 Chemical equilibrium FOCUS 7 Quantum theory FOCUS 8 Atomic structure and spectra FOCUS 9 Molecular structure FOCUS 10 Molecular symmetry FOCUS 11 Molecular spectroscopy FOCUS 12 Magnetic resonance FOCUS 13 Statistical thermodynamics FOCUS 14 Molecular interactions FOCUS 15 Solids FOCUS 16 Molecules in motion FOCUS 17 Chemical kinetics FOCUS 18 Reaction dynamics FOCUS 19 Processes at solid surfaces Resource section 1 Common integrals 2 Units 3 Data 4 Character table

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,
,FUNDAMENTAL CONSTANTS

Value
Constant Symbol
Power of
Units
10
Speed of light c 2.997 924 108 m s-1
58*
Elementary charge e 1.602 176 10-19 C
565
Planck's constant h 6.626 069 10-34 Js
57
1.054 571 10-34 Js
726
Boltzmann's constant k 1.380 6488 10-23 J K-1
Avogadro's constant NA 6.022 141 1023 mol-1
29
Gas constant R= 8.314 4621 J K-1
NAk mol-1
Faraday's constant F= 9.648 533 104 C mol-1
NAe 65
Mass
Electron me 9.109 382 10-31 kg
91
Proton mp 1.672 621 10-27 kg
777
Neutron mn 1.674 927 10-27 kg
351
Atomic mass constant mu 1.660 538 10-27 kg
921
Vacuum permeability μ0 4π* 10-7 J s2 C-2
m-1

, Vacuum permittivity ε0 = 1/ 8.854 187 10-12 J-1 C2
μ0c2 817 m-1
4πε0 1.112 650 10-10 J-1 C2
056 m-1
Bohr magneton 9.274 009 10-24 J T-1
68
Nuclear magneton 5.050 783 10-27 J T-1
53
Proton magnetic μp 1.410 606 10-26 J T-1
moment 743
g-Value of electron ge 2.002 319
304
Magnetogyric ratio
Electron -1.001 159 1010 C kg-1
652
Proton 2.675 222 108 C kg-1
004
Bohr radius 5.291 772 10-11 m
109
Rydberg constant 1.097 373 105 cm-1
157
13.605 692 eV
53
Fine-structure constant 7.297 352 10-3
5698
α-1 1.370 359 102
990 74
Stefan-Boltzmann 5.670 373 10-8 W m-2
constant K-4
Standard acceleration of g 9.806 65* m s-2
free fall
Gravitational constant G 6.673 84 10-11 N m2
kg-2
* Exact value. For current values of the constants, see the National Institute of Standards

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