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Summary - org chem 101

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organic chemistry notes about ](alcohols, phenols and thiols)

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Naming ofalcohols

OH I alkantol Iupac primaryalcohol bin connectedwithonecarbon



CHzon methanol
Ctbcha on ethanol c f carbinol carboncontaininghydroxylgroup

wedon'tneedtowritethe fortheonwhenwehavetorecarbons
Secondaryalcohol carbinolconnected withtwocarbons




on 1 butanol tertiary alcohol carbinol connectedwiththreecarbons
c

it cti cti
cts

2
on
s
3 methyl a butanol cts
ii
c chs carbinol carbonthathasonattached


b 2 methyl 4 octanol
s
a
mm ans 3 methylcyclohexane primarycarbon secondaryalcohol

0
cuz ch ch cha on a butane l ol tertiarycarbon


chg c c cha Ila s s pentyne 1 ol Reactionofalcohol



alkyl alcohol common 1 Dehydration of alcohol RemovalofH2O
them
removed Hao
CHzOH methylalcohol cHzcHzoH ethylalcohol alcohol so alkene on stag
cha
theta cts
qt's Hao
on

cha cha cha on propylalcohol cha ctichante't cuz ch alkene
cha Hao secondaryalcohol


chs It cuz isopropylalcohol
chs chs
isobutylgroup

CH
oh c on
oh
tertbutylalcohol
oh
oh
j tert easiestonetoloseH2otertiary secondary primary

alcohol
cyclohexyl atty It cha ah feta s cha ch cha cti onebranchminor
soon otis ch ch ca twobranchmajor
Namingphenol acid
m hydroxybenzoic zaitsev'srule the
alkenewithmorebranches ismajorBless isminor

OH O a
azeetrule
c't
3 chlorophenol saz ga cha atlanta chs É ch chacha sbranch major
O O m chlorophenol
Iupac
common ch uts ch ch ch abranchminor
g
Theno OH
oh benzaldehyde
a hydroxy
Br O sp hydroxybenzaldehyde
g Ho
Br 2,4stribromophenol Iupac

notes carboxylicgroup aldehyde alcohol
Feton
FHas abranch is called hydroxy

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