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AQA-7405-3-CHEMISTRY FINAL MARK SCHEME PAPER 3-A LEVEL-Jun24

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AQA-7405-3-CHEMISTRY FINAL MARK SCHEME PAPER 3-A LEVEL-Jun24-v1.0. Question Answers Additional comments/Guidelines Mark 1.1 M1 skeletal formula of organic product M2 rest of equation M1 Need H on alcohol OH M1 Allow O–H for alcohol OH M2 for correct formulae for 2-hydroxybenzenecarboxylic acid and methanol on left and H2O on right M2 Allow C7H6O3/HOC6H4COOH and CH4O Ignore additional non-skeletal structures for ester (assume it is working out) Allow Kekulé structures for rings 2 (2 x AO2) Question Answers Additional comments/Guidelines Mark 1.2 Ethanoic anhydride/It is less/not corrosive OR Ethanoic anhydride/It does not form strong acid/HCl /(only) forms weak/ethanoic/carboxylic acid OR Ethanoic anhydride/It is less/not vulnerable to hydrolysis Allow reverse argument for ethanoyl chloride e.g. ethanoyl chloride is (more) corrosive Ignore cost / less volatile / products are less harmful / safer / toxic / produces toxic fumes Ignore references to less/more exothermic/violent/vigorous 1 (1 x AO1) Question Answers Additional comments/Guidelines Mark 1.3 (nucleophilic) addition-elimination Ignore esterification / acylation 1 (1 x AO1) 000014 Page 14 of 33 ALL THE BEST MARK SCHEME – A-LEVEL CHEMISTRY – 7405/3 – JUNE 2024 15 Question Answers Additional comments/Guidelines Mark 1.4 catalyst Ignore proton donor / heterogeneous / homogeneous Allow speeds up reaction / lowers activation energy 1 (1 x AO3) Question Answers Additional comments/Guidelines Mark 1.5 boiling points are above 85 °C Allow product(s) or reactant(s) or named product(s) or reactant(s) boiling points are above 85 °C Allow none of them would boil / mixture would not boil / do not need to boil the mixture Allow no volatile reagent(s)/product(s)/reactant(s) Ignore reference to mixture/substances not evaporating / vaporising 1 (1 x AO3) 000015 Page 15 of 33

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000001




AQA
MARK SCHEME



A-level
CHEMISTRY
7405/3




T
Paper 3




ES
Mark scheme

June 2024

Version: 1.0 Final
B
E
TH
LL
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Page 1 of 33

,000002


MARK SCHEME – A-LEVEL CHEMISTRY – 7405/3 – JUNE 2024



Mark schemes are prepared by the Lead Assessment Writer and considered, together with the relevant
questions, by a panel of subject teachers. This mark scheme includes any amendments made at the
standardisation events which all associates participate in and is the scheme which was used by them in
this examination. The standardisation process ensures that the mark scheme covers the students’
responses to questions and that every associate understands and applies it in the same correct way.
As preparation for standardisation each associate analyses a number of students’ scripts. Alternative
answers not already covered by the mark scheme are discussed and legislated for. If, after the
standardisation process, associates encounter unusual answers which have not been raised they are
required to refer these to the Lead Examiner.


It must be stressed that a mark scheme is a working document, in many cases further developed and
expanded on the basis of students’ reactions to a particular paper. Assumptions about future mark
schemes on the basis of one year’s document should be avoided; whilst the guiding principles of




T
assessment remain constant, details will change, depending on the content of a particular examination
paper.




ES
No student should be disadvantaged on the basis of their gender identity and/or how they refer to the
gender identity of others in their exam responses.


B
A consistent use of ‘they/them’ as a singular and pronouns beyond ‘she/her’ or ‘he/him’ will be credited in
exam responses in line with existing mark scheme criteria.
E
Further copies of this mark scheme are available from aqa.org.uk
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A




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MARK SCHEME – A-LEVEL CHEMISTRY – 7405/3 – JUNE 2024



AS and A-Level Chemistry
Mark Scheme Instructions for Examiners

1. General
The mark scheme for each question shows:
• the marks available for each part of the question
• the total marks available for the question
• the typical answer or answers which are expected
• extra information to help the examiner make his or her judgement and help to delineate what




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is acceptable or not worthy of credit or, in discursive answers, to give an overview of the area
in which a mark or marks may be awarded.




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The extra information in the ‘Comments’ column is aligned to the appropriate answer in the left-
hand part of the mark scheme and should only be applied to that item in the mark scheme.
You should mark according to the contents of the mark scheme. If you are in any doubt about
applying the mark scheme to a particular response, consult your Team Leader.
At the beginning of a part of a question a reminder may be given, for example: where

diagram or at a different place on the script.
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consequential marking needs to be considered in a calculation; or the answer may be on the

In general the right-hand side of the mark scheme is there to provide those extra details which
might confuse the main part of the mark scheme yet may be helpful in ensuring that marking is
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straightforward and consistent.
The use of M1, M2, M3 etc in the right-hand column refers to the marking points in the order in
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which they appear in the mark scheme. So, M1 refers to the first marking point, M2 the second
marking point etc.


2. Emboldening
2.1 In a list of acceptable answers where more than one mark is available ‘any two from’ is
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used, with the number of marks emboldened. Each of the following bullet points is a
potential mark.
2.2 A bold and is used to indicate that both parts of the answer are required to award the
mark.
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2.3 Alternative answers acceptable for a mark are indicated by the use of OR. Different terms
in the mark scheme are shown by a / ; eg allow smooth / free movement.


3. Marking points
3.1 Marking of lists
This applies to questions requiring a set number of responses, but for which students
have provided extra responses. The general ‘List’ principle to be followed in such a
situation is that ‘right + wrong = wrong’.
Each error / contradiction negates each correct response. So, if the number of error /
contradictions equals or exceeds the number of marks available for the question, no
marks can be awarded.


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MARK SCHEME – A-LEVEL CHEMISTRY – 7405/3 – JUNE 2024



However, responses considered to be neutral (often prefaced by ‘Ignore’ in the mark
scheme) are not penalised.




For example, in a question requiring 2 answers for 2 marks:

Incorrect
Correct answers (i.e.
Mark (2) Comment
answers incorrect rather
than neutral)

1 0 1




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They have not exceeded the maximum
1 1 1 number of responses so there is no
penalty.




ES
They have exceeded the maximum number
1 2 0 of responses so the extra incorrect
response cancels the correct one.

2 0 2

2 1 1
B
2 2 0
E
3 0 2 The maximum mark is 2

The incorrect response cancels out one of
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3 1 1 the two correct responses that gained
credit.

Two incorrect responses cancel out the two
3 2 0
marks gained.

3 3 0
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3.2 Marking procedure for calculations
Full marks should be awarded for a correct numerical answer, without any working
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shown, unless the question states ‘Show your working’ or ‘justify your answer’. In this
case, the mark scheme will clearly indicate what is required to gain full credit.
If an answer to a calculation is incorrect and working is shown, process mark(s) can
usually be gained by correct substitution / working and this is shown in the ‘Comments’
column or by each stage of a longer calculation.


3.3 Errors carried forward, consequential marking and arithmetic errors
Allowances for errors carried forward are most likely to be restricted to calculation
questions and should be shown by the abbreviation ECF or consequential in the marking
scheme.



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