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AQA-7404-2-CHEMISTRY QUESTION PAPER 2-AS LEVEL-ORGANIC AND PHYSICAL CHEMISTRY-21May24.

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0 1 This question is about the analysis of organic compounds. 0 1 . 1 Table 1 shows the results of chemical tests on three organic compounds. Complete the empty boxes in the table. Table 1 Chemical test Add bromine water orange to colourless no visible change no visible change bubbles of gas no visible change Warm with Fehling’s solution no visible change no visible change [3 marks] Page 2 of 36 CHEMISTRY 3 *03* Turn over ► IB/M/Jun24/7404/2 Do not write outside the box 0 1 . 2 0.500 g of a hydrocarbon is analysed. The hydrocarbon contains 0.450 g of carbon. Calculate the empirical formula of this hydrocarbon. [3 marks] Empirical formula Turn over for the next question Page 3 of 36 CHEMISTRY 4 *04* IB/M/Jun24/7404/2 Do not write outside the box 0 2 This question is about infrared spectroscopy. 0 2 . 1 Compounds A and B both have the molecular formula C4H8O2 Figure 1 shows the infrared spectra of compounds A and B. Use the infrared spectra to deduce a possible structural formula for compound A and a possible structural formula for compound B. [2 marks]

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000001




AQA
Please write clearly in block capitals.

Centre number Candidate number


Surname

Forename(s)

Candidate signature
I declare this is my own work.


AS



Y
CHEMISTRY
Paper 2 Organic and Physical Chemistry TR
IS
Tuesday 21 May 2024 Morning Time allowed: 1 hour 30 minutes
Materials
EM

For Examiner’s Use
For this paper you must have:
• the Periodic Table/Data Sheet, provided as an insert (enclosed) Question Mark
• a ruler with millimetre measurements 1
• a scientific calculator, which you are expected to use where appropriate.
2

Instructions 3
H



• Use black ink or black ball-point pen. 4
• Fill in the boxes at the top of this page. 5
• Answer all questions.
C




• You must answer the questions in the spaces provided. Do not write outside 6
the box around each page or on blank pages. 7
• If you need extra space for your answer(s), use the lined pages at the end of Section B
this book. Write the question number against your answer(s).
• All working must be shown. TOTAL
• Do all rough work in this book. Cross through any work you do not
want to be marked.

Information
• The marks for questions are shown in brackets.
• The maximum mark for this paper is 80.

Advice
You are advised to spend about 65 minutes on Section A and 25 minutes on Section B.




IB/M/Jun24/G4001/V7 7404/2
Page 1 of 36

,000002

2
Do not write
outside the
Section A box


Answer all questions in this section.


0 1 This question is about the analysis of organic compounds.

0 1 . 1 Table 1 shows the results of chemical tests on three organic compounds.

Complete the empty boxes in the table.

Table 1




Y
Chemical test




Add bromine orange to
TR
IS
no visible change
water colourless
EM


no visible change bubbles of gas no visible change
H



Warm with
Fehling’s no visible change no visible change
C




solution



[3 marks]




*02*
IB/M/Jun24/7404/2
Page 2 of 36

,000003

3
Do not write
outside the
0 1 . 2 box
0.500 g of a hydrocarbon is analysed.
The hydrocarbon contains 0.450 g of carbon.

Calculate the empirical formula of this hydrocarbon.
[3 marks]




Y
TR
IS
EM


Empirical formula 6
H
C




Turn over for the next question




Turn over ►


*03*
IB/M/Jun24/7404/2
Page 3 of 36

, 000004

4
Do not write
outside the
0 2 box
This question is about infrared spectroscopy.

0 2 . 1 Compounds A and B both have the molecular formula C4H8O2

Figure 1 shows the infrared spectra of compounds A and B.

Use the infrared spectra to deduce a possible structural formula for compound A and
a possible structural formula for compound B.
[2 marks]

Figure 1




Y
TR
IS
EM
H
C




Possible structural formula of A Possible structural formula of B




*04*
IB/M/Jun24/7404/2
Page 4 of 36

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