Pearson Edexcel Level 3 GCE Chemistry Advanced PAPER 1 Advanced Inorganic and Physical Chemistry

PleaseEcheckEtheEexaminationEdetailsEbelowEbeforeEenteringEyourEcandidateEinformatio
n
CandidateE surname OtherEnames

CentreE Number CandidateENumber
Pearson Edexcel E E



Level 3 GCE E E




TimeE 1EhourE45Eminutes
PaperEref
erence 9CH0/01
Chemistry
Advanced
PAPER 1: Advanced Inorganic and Physical Chemistry
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CandidatesEmustEhave:EScientificEcalculator TotalEMarks
DataE BookletERule
r

Instructions
• Use black ink or black ball-point pen.
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in the boxes at the top of this page with your name,
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number and candidate number.
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•• Answer all questions.
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Answer the questions in the spaces provided
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– thereEmayEbeEmoreEspaceEthanEyouEneed.
• ShowEallEyourEworkingEinEcalculationsEandEincludeEunitsEwhereEappropriate.

Information
• The total mark for this paper is 90.
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• For the question marked with an asterisk (*), marks will be awarded for your ability to str
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omEeachEotherEwhereEappropriate.
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Advice

•• Read each question carefully before you start to answer it.C
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heck your answers if you have time at the end.
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P65463A
©2021E PearsonE EducationE Ltd.

1/1/1/1/1/

, AnswerEALLEquestions.

SomeEquestionsEmustEbeEansweredEwithEaEcrossEinEaEbox .
IfEyouEchangeEyourEmindEaboutE anEanswer,EputEaElineE throughEtheEboxEa
ndEthenEmarkEyourEnewEanswerEwithEaEcross .

1 ThisE isE aE questionE aboutE atoms,E isotopesE andE ions.

(a) WhichE ofE theE followingE pairsE ofE ionsE isE isoelectronic?
(1)
AE N3–EandECl–

B O2–EandES2–
E E



CE Na+EandEK+
E



D Na+EandEMg2+


(b) WhichE isE aE correctE definitionE ofE relativeEisotopicE mass?
(1)
A theE weightedE meanE massE ofE anE atomE ofE anE elementE relativeE toE oneE twelfthE ofEth
eEmassEofEanEatomEofEtheEisotopeEcarbon-12
B theE massE ofE oneE atomE ofE anE isotopeE relativeE toE oneE twelfthE ofE theE massE ofE anEat
omEofEtheEisotopeEcarbon-12
C theE weightedE meanE massE ofE anE atomE ofE anE elementE relativeE toE 12EgE ofE theEis
otopeEcarbon-12
D theEmassEofEoneEatomEofEanEisotopeErelativeEtoEtheEmassEofE12EgEofEtheEiso
topeEcarbon-12




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,(c) TheEpercentageEcompositionEofEtheEtwoEbromineEisotopesEinEaEsampleEisEgivenEinEth
eEtable.


Isotope RelativeEisotopicEmass PercentageEabundance

bromine-79 78.918 50.52

bromine-81 80.916 49.48


CalculateE theE relativeE atomicE massE ofE bromineE inE thisEsample.EGiveE
yourEanswerEtoEtwoEdecimalEplaces.
(2)




(TotalEforEQuestionE1E=E4Emarks)




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TurnEover

, 2 BariumEionsEcanEbeEidentifiedEbyEtheirEflameEcolour.
(a) WhichEofEtheEfollowingEshouldEbeEusedEforEaEflameEtestEonEbariumEcarbonate?
A
(1)E
ironEwireEandEwater
B ironE wireE andE concentratedE hydrochloricE acid

C nichromeE wireE andE water

D nichromeE wireE andE concentratedE hydrochloricE acid


(b) WhatEcolourEdoEbariumEionsEgiveEinEaEflameEtest?
(1)
A green
B lilac

C red

D yellow


(c) AE flameE testE wasE carriedE outE onE aE mixtureE ofE bariumE chlorideE andE magnesiumE chloride.
HowEdoesEtheEpresenceEofEmagnesiumEionsEaffectEtheEappearanceEofEtheEflameEcolourEofEb
ariumEions?
(1)
A theE colourE isE moreE intense
B aEbrightEwhiteEcolourEcompletelyEmasksEtheEbariumEcolour
C thereEisEnoEchange

D theEbariumEcolourEisEdecreasedEbyEtheEwhiteEmagnesiumEflameEcolour



(TotalEforEQuestionE2E=E3Emarks)




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