COMPLETE SOLUTIONS VERIFIED LATEST UPDATE
[A]<=>[B]
at T=273K [A]>[B]
at T=330K [B]>[A]
at [A]=[B]=1M, dH?0 dS?0
dG=dH-TdS
dG0=-RTlnk
at T=273k, k<1, dG>0
at T=330, k>1, dG<0
dG decreases as T increases
dS is positive because -TdS has to be negative for dG to decrease
dH has to be positive because dG is positive -> 0
conclusion: dH>0, dS>0
ascorbic acid (H2C6H6O6) can be protonated twice with 2 different pKa's
H2C6H6O6 <=> H+ + HC6H6O6- at pKa=4.1
HC6H6O6- <=> H+ + C6H6O62- at pKa=11.8
pH=pKa+log([B]/[A])
when pH is less than pKa, protonation is favored
in a case where pH is less than pKa, the species with lower pKa will be more protonated
at pH=3, H2C6H6O6 is more common
, which of the following tripeptides has both a net charge of -1 at pH=7 and 6
oxygen atoms
RPA
EDI
SDA
KDI
EMI
can't be SDA because Serine has a hydroxyl group
N-term RPA C-term
+ +00 -
N-term EDI C-term
+ --0 -
N-term KDI C-term
+ +-0 -
N-term EMI C-term
+ -00 -
EMI has -1 charge
which of the following heptad sequences corresponding to amino acid position a-
g above is most likely to be found in a coiled coil
KILHAVI
PGGPGGG
WIVFILV