and Their Reactions"
1. Introduction to Organic Chemistry
Definition and Importance:
Organic chemistry focuses on the structure, properties, and reactions of organic
compounds, primarily those containing carbon. Carbon’s unique ability to form
stable covalent bonds with other elements (C, H, O, N, etc.) creates a vast array of
compounds crucial in everyday life, such as medicines, fuels, plastics, and more.
Functional Groups:
Functional groups are specific groupings of atoms within molecules that determine
their chemical reactivity. For example, the hydroxyl group (-OH) in alcohols is
responsible for their solubility in water and reactivity in oxidation reactions.
Application in Real Life:
Understanding functional groups allows chemists to design drugs, synthesize
materials, and analyze biological pathways.
2. Common Functional Groups
Hydrocarbons
Alkanes (C-C single bonds):
Nonpolar, relatively unreactive due to strong sigma bonds.
Examples: Methane (CH₄), Ethane (C₂H₆).
Reactions: Combustion to produce CO₂ and H₂O.
, Alkenes (C=C double bonds):
Unsaturated hydrocarbons, more reactive due to the pi bond.
Examples: Ethene (C₂H₄), Propene (C₃H₆).
Reactions: Addition of halogens, hydrogenation.
Alkynes (C≡C triple bonds):
Unsaturated, reactive due to the pi bonds.
Examples: Ethyne (C₂H₂), Propyne (C₃H₄).
Reactions: Electrophilic addition, oxidation.
Alcohols (-OH)
Physical Properties:
Polar molecules with hydrogen bonding, leading to high boiling points and
solubility in water.
Chemical Properties:
Oxidation:
Primary alcohols oxidize to aldehydes and then carboxylic acids.
Secondary alcohols oxidize to ketones.
Tertiary alcohols resist oxidation.
Example: Oxidation of ethanol to acetic acid using potassium dichromate.
Aldehydes and Ketones (-CHO and >C=O)
Aldehydes are more reactive due to the hydrogen atom bonded to the carbonyl
carbon.