HEAMoprN Amics AND tSTATE OF $YSTGM
THEeMoCIemisTRY onditlom im vohch System
*SSEM GU2ROUNDiNG
Anyrünog othiy hor
wnd observaen systen. by speiçie ydun Aemp. pressoe
’STATE FUNc\ONS :
bsepaod b wala Iboundau ydepend y a state o sYstem,
Diahavmit Acdalsatiç Indpenane ypath odoptad to
HOCsHUGs
bl NG heat o
Sysr GUrY. bl sys. sUyr.
EP, V,T, UE, S, H, G
)opeN SYSTeM : 9PATH FUNCTÍONS
9 dupend m patth.
) UOSEO SYSTEM Yhore & Heat ’ path uncs.
3)1SOLATED SYStEm : n t e mass
nor hua exehonse
H(anthoupy) =Gngy centnt at
>Perfecty soltad UnisQ Corgtmt presSVrS
System (Sys +SUr) H =U+ V
DCenstt ressUYe
PressurR,
Is im h Qabm n h c t h n
*EreNSve iTEN)SIVE PeOPEeTY 3)For hnical ni
popor4ieg chonge onchomgngant
system ’ txTenslve (additive) 20
Snch do not iNTeNS0Ve (T; (bng Product eatmt
gaseloS
Tntensiue Aroe Extengi ee meles mole
Density, m.e, B., Tem,mass vow)"H eAT (a or a):
Corc),pH, sunjae Tonien enalpy (H),PE,
vlSçoslty, .I, Kp, k .e, Heat capaclty,
ys. tS GUrr, n arcant
Irt.enos9 entopyc,
AUe oncerraenn
Gibbs ersya),lesisto
torns Intosse
enegle intonsty Sys. Syos.
Extensue
Suis. Sys.e
Extensi
Sys
gainle (+)
censtons
spectc' or 'rda Girtorsi
yintensie
, Pext ’SPECTÁC HEAT CAPATY
dh-Pot AV Cotont
m.aT rals temp
Pressure againt wich gas cys. by 19
por fcn hoore ms(T,-T
Pot OR
Preagure hich is permognng GHeas sup led yo systam hanng
mass m' Gpecffe huat 's
’moLAR HeAT CAPAutY
Whem Paxt vaalte.
2
ndT
Amol o Sys. by 1°
Tdo =nCaT
1atm-Lt=104
molagn Heot Capadty (C)
At consEomt At constamt
procsUro
GHat amd ngcre lsth a (Cu)
boundosyhemomumen:
Sys. SuY Ong nole o to Hat suppied
1mol idal gos
Taise its temp-by10 ase it temp by 1°
On (onstont
at coms tont prrassoTe
’ SIGN CONveNtiON:
)hcy don bysterm =-e Cp >Cv
were dn mSy S. =+ e
2eatglaam by syS =-e =0 )Inereang
Heab absorbe by seen te
vaise temp
*FIRST LAN OF THeRmOpYNAmies:
At nstmt vone -
Cv Comst
ayic process: g=-, u:O aU=ncvdT
JsothNnal a-Ww=0
Adolsate prOreSs _bUat,,=O At onstnt poeSsure
Jsochorie procoss : s0-0,', W=0
AHeAT CAPATY -
4syStom by ng deg ree"
da,
lepv t ansc
THEeMoCIemisTRY onditlom im vohch System
*SSEM GU2ROUNDiNG
Anyrünog othiy hor
wnd observaen systen. by speiçie ydun Aemp. pressoe
’STATE FUNc\ONS :
bsepaod b wala Iboundau ydepend y a state o sYstem,
Diahavmit Acdalsatiç Indpenane ypath odoptad to
HOCsHUGs
bl NG heat o
Sysr GUrY. bl sys. sUyr.
EP, V,T, UE, S, H, G
)opeN SYSTeM : 9PATH FUNCTÍONS
9 dupend m patth.
) UOSEO SYSTEM Yhore & Heat ’ path uncs.
3)1SOLATED SYStEm : n t e mass
nor hua exehonse
H(anthoupy) =Gngy centnt at
>Perfecty soltad UnisQ Corgtmt presSVrS
System (Sys +SUr) H =U+ V
DCenstt ressUYe
PressurR,
Is im h Qabm n h c t h n
*EreNSve iTEN)SIVE PeOPEeTY 3)For hnical ni
popor4ieg chonge onchomgngant
system ’ txTenslve (additive) 20
Snch do not iNTeNS0Ve (T; (bng Product eatmt
gaseloS
Tntensiue Aroe Extengi ee meles mole
Density, m.e, B., Tem,mass vow)"H eAT (a or a):
Corc),pH, sunjae Tonien enalpy (H),PE,
vlSçoslty, .I, Kp, k .e, Heat capaclty,
ys. tS GUrr, n arcant
Irt.enos9 entopyc,
AUe oncerraenn
Gibbs ersya),lesisto
torns Intosse
enegle intonsty Sys. Syos.
Extensue
Suis. Sys.e
Extensi
Sys
gainle (+)
censtons
spectc' or 'rda Girtorsi
yintensie
, Pext ’SPECTÁC HEAT CAPATY
dh-Pot AV Cotont
m.aT rals temp
Pressure againt wich gas cys. by 19
por fcn hoore ms(T,-T
Pot OR
Preagure hich is permognng GHeas sup led yo systam hanng
mass m' Gpecffe huat 's
’moLAR HeAT CAPAutY
Whem Paxt vaalte.
2
ndT
Amol o Sys. by 1°
Tdo =nCaT
1atm-Lt=104
molagn Heot Capadty (C)
At consEomt At constamt
procsUro
GHat amd ngcre lsth a (Cu)
boundosyhemomumen:
Sys. SuY Ong nole o to Hat suppied
1mol idal gos
Taise its temp-by10 ase it temp by 1°
On (onstont
at coms tont prrassoTe
’ SIGN CONveNtiON:
)hcy don bysterm =-e Cp >Cv
were dn mSy S. =+ e
2eatglaam by syS =-e =0 )Inereang
Heab absorbe by seen te
vaise temp
*FIRST LAN OF THeRmOpYNAmies:
At nstmt vone -
Cv Comst
ayic process: g=-, u:O aU=ncvdT
JsothNnal a-Ww=0
Adolsate prOreSs _bUat,,=O At onstnt poeSsure
Jsochorie procoss : s0-0,', W=0
AHeAT CAPATY -
4syStom by ng deg ree"
da,
lepv t ansc
