3/24
Haloalkane &
Haloarines
(AItyt haud)
Haloakane:
when hycqgun
halogen, hn
alkane dusplau ty
by he mu oHm haloaJkane
In hue omp^, nlogen bonclud uuth sp' hybid ubon
q- CHa- I J0do mdhane oH mthyt iodid
Jaswicahon halogen duvahuw
Haloqn duuvahves bos
Dihaloduxi vatiue Polyhalodwnivahe
monohadoduHVahue
nOHMW (n)
RIkyl hauce
OH Prumay (c -x) ISo Ciso)
oOoublt
Singte
sp
sp²
HaloalkNe -x) neo (neo)
|Oiple |2 double
(a'c
seCondamy
SP
R-CH - X
Tohay (3c -a)too L
sp xE,U,6h ,I
ue
haude OihaloduHivati
vinyt
-X
ChH3-CH, TUminalohe
sp
Geminal
dihai du
vidnal
dihaid di haidog C- C- C -
AIlyl hai d c-cca
CHy
|
-CH -CH, -A
Ayl naud
sps
CAUyucune
dichioide)
(RIkyLune
ichlorId)2
OHoLA
OH
phnyi haud
HaloaHNe)
Benut hau
CH- X
daosys
, halogen In
cabon
a aud x
Vinyl haida: Whn double bond tnt at
untaH chaun mn my unyl halud
E3> Vinyl hloude
Nuy naudu :uhn double
hn hy
bond nd
vu
a he p
Ay! h alida
caxbon halogen
unta ch un, calld
CH CH - CHy -
mON! KLahue man uny
chloicli
)
9 Wny Alyl chloid is
mau's uhy it is uu cue
is has kuonanu stabiuty
Vinyl NOHcu hat's why it
is
ahile A yl
tuOnid become table gen Ucaing a ion
mOU Huaive.
- ARl haud oH hauo akUnes: whn hao Qun dindly bondud with benne ing
ayi hud oH haloUhu.
hn it Is Caud
WOHO bnene.
bnzee bon Qp bondud wuth he
Bnyl Haud: wuhn halogun 2
same caKbon. hn hy aL cad Bn y haud
- u:
due to RUonaNe.
NOmen latuu 2 Iommism
Common : haide
JUPA C : Haloalkane
CH3- I melhyl Iodide (c)
JOdo mlhane Cz)
CH3- CH2 u Ehyl tOudu cc)
chuoHo clhane u)
BH Is0pHoPy !bM omud cc
CHg- CH
CHg 9- BHomo pHOpne I)
IsDmeri Sm i Hdoakane show h un, pouthon opha! isomism.
hu
Cs Hi2 t (Photohalog ination)
O CHy - C- C-C- C- Q C- C- c C-C C- C
de (c)
n- Pentyl chuoni sec- Penty! chioIde cc)hek Scer Pentyl chlondeC)
1- chUOH o pen tane u) 9-chuot Pntane cu)
3- huorO perlane ()
, m
tot pentyt oice (c) 1-WoHO- 2
pnty uOdu ce)
1-
ISO
chlOM0-3 mehy punlane a) munyi butane CI) 2- UOMO 2 mltye -
butane u)
metye
buun ec)
C
C
Pntytchlotico cc)
nto-
J-hUOHO -2,2-dimeny! pHopane a)
tuik namu & rdenhjy 23
2-BHOmno butane
n- 6utyi BHOcu Sec- Buyt BHomid
J- BHomo Bulune
J'C-C-
C
C- BM C - - 2
c 2- BHOmo -2- methy2 pHopane
J-84omo -2- muthyl
PHqpane
iso- buy
buty !8HOmidr
C- C -C-c
1, 1- ichjoHObutane 2,3- DichOMO butune
C-C - C-C
1,2- DihdoHo butane
4,4- DichloHobutane
1,2-DichlOHO2 mny'pHopan
C-C - C- c
a- C-Ç - C-a
C
1,3- DichoMO butone
1,3- dictlOMO- 2- metthy pHopau
C-C -C-c 20mOitnon3
a,2-DicOHObulane
Haloalkane &
Haloarines
(AItyt haud)
Haloakane:
when hycqgun
halogen, hn
alkane dusplau ty
by he mu oHm haloaJkane
In hue omp^, nlogen bonclud uuth sp' hybid ubon
q- CHa- I J0do mdhane oH mthyt iodid
Jaswicahon halogen duvahuw
Haloqn duuvahves bos
Dihaloduxi vatiue Polyhalodwnivahe
monohadoduHVahue
nOHMW (n)
RIkyl hauce
OH Prumay (c -x) ISo Ciso)
oOoublt
Singte
sp
sp²
HaloalkNe -x) neo (neo)
|Oiple |2 double
(a'c
seCondamy
SP
R-CH - X
Tohay (3c -a)too L
sp xE,U,6h ,I
ue
haude OihaloduHivati
vinyt
-X
ChH3-CH, TUminalohe
sp
Geminal
dihai du
vidnal
dihaid di haidog C- C- C -
AIlyl hai d c-cca
CHy
|
-CH -CH, -A
Ayl naud
sps
CAUyucune
dichioide)
(RIkyLune
ichlorId)2
OHoLA
OH
phnyi haud
HaloaHNe)
Benut hau
CH- X
daosys
, halogen In
cabon
a aud x
Vinyl haida: Whn double bond tnt at
untaH chaun mn my unyl halud
E3> Vinyl hloude
Nuy naudu :uhn double
hn hy
bond nd
vu
a he p
Ay! h alida
caxbon halogen
unta ch un, calld
CH CH - CHy -
mON! KLahue man uny
chloicli
)
9 Wny Alyl chloid is
mau's uhy it is uu cue
is has kuonanu stabiuty
Vinyl NOHcu hat's why it
is
ahile A yl
tuOnid become table gen Ucaing a ion
mOU Huaive.
- ARl haud oH hauo akUnes: whn hao Qun dindly bondud with benne ing
ayi hud oH haloUhu.
hn it Is Caud
WOHO bnene.
bnzee bon Qp bondud wuth he
Bnyl Haud: wuhn halogun 2
same caKbon. hn hy aL cad Bn y haud
- u:
due to RUonaNe.
NOmen latuu 2 Iommism
Common : haide
JUPA C : Haloalkane
CH3- I melhyl Iodide (c)
JOdo mlhane Cz)
CH3- CH2 u Ehyl tOudu cc)
chuoHo clhane u)
BH Is0pHoPy !bM omud cc
CHg- CH
CHg 9- BHomo pHOpne I)
IsDmeri Sm i Hdoakane show h un, pouthon opha! isomism.
hu
Cs Hi2 t (Photohalog ination)
O CHy - C- C-C- C- Q C- C- c C-C C- C
de (c)
n- Pentyl chuoni sec- Penty! chioIde cc)hek Scer Pentyl chlondeC)
1- chUOH o pen tane u) 9-chuot Pntane cu)
3- huorO perlane ()
, m
tot pentyt oice (c) 1-WoHO- 2
pnty uOdu ce)
1-
ISO
chlOM0-3 mehy punlane a) munyi butane CI) 2- UOMO 2 mltye -
butane u)
metye
buun ec)
C
C
Pntytchlotico cc)
nto-
J-hUOHO -2,2-dimeny! pHopane a)
tuik namu & rdenhjy 23
2-BHOmno butane
n- 6utyi BHOcu Sec- Buyt BHomid
J- BHomo Bulune
J'C-C-
C
C- BM C - - 2
c 2- BHOmo -2- methy2 pHopane
J-84omo -2- muthyl
PHqpane
iso- buy
buty !8HOmidr
C- C -C-c
1, 1- ichjoHObutane 2,3- DichOMO butune
C-C - C-C
1,2- DihdoHo butane
4,4- DichloHobutane
1,2-DichlOHO2 mny'pHopan
C-C - C- c
a- C-Ç - C-a
C
1,3- DichoMO butone
1,3- dictlOMO- 2- metthy pHopau
C-C -C-c 20mOitnon3
a,2-DicOHObulane
