Chemieal fquitibium
AH>O
Vapow
AH <O
sahom. Rate of condesahon.
At eqm, Rase of vapouu
costant
At costant emp.
Vapous Preswne
Preswe oß vapoy lig uid ahen ki'quid ano
Vapour are in quibum,
o facrs afteching Vapowr Bessne
Ve. ’ tenp. dep endant VP & Temp
A
ve (VP): A6) e
(BP): A<82e
Tenp temp.
Boiling
Point
2.303R
hee f, and , ae vapos pttemwe at
and T, tempuahire Tesp.
d (ln P)
dT RT2 oio hen åe
(6) VP
Snter moteular
attrachom
Volable
VP ‘ Snhesmal euas ature
boiling Point 4 a
, Volehve
Velable
solvent soute
ve of Aon maybe ehang
(ve) due to mixing
NO, H10 + HNO,
[pomenibophnol|
Snha- H-bmd Snes H-bond
VP ‘
lalcohol bneaks H-bmd
Exenal Presune. vP
(AH>O)
Amount prepuny Helhing (at malhing point cf
auLea () Solid iquid Cyshalline solid ).
frcinq (BH co)
AF equii bium,
Roie f malhing (yuin) - Rae os reeaing.
Volahle iqid volakle
AF maing point of enystalline (ohd
(Solvent ) free xing print of iyuid.
NoTmal
facos alkehing
Sea (ve).
wats wats i Exnal prLsWe :
Solid
iquid (expansin) Melhing Eat. P‘
o.I H Na cl (e) 0. 0S M 0.01 M
(ve) v'quid (eon hachn )
mthng e
D.2 mole in
0. 03 mole.
0. mole Ex : watks (soid) Was (liquid)
HË0 H10 + Na cl (susfece ka1sen) Ice
(due to in -dipole Conhhachon
in kenachon) igh deni
&+
Vacant fxpansion H-o
A
Jpace
* (v), H (ww densiy)
Solvent
Volahle ( 4 non- volakte (s)
, tethng of Helhing
porint
Tee ü) Smpunily
. volahle and P‘
Volahle +
Nom ’ Ve
Aolue
an solaed Ayskm , wats Fne ing
and in equil'bnum Pornt
(at o'e )
and mas of Hao Fr zing foint: The tmp. at which Ve (4) bcsmes
Mass oh ce
eons tant equal to VP. ().
iy Tempuahre. (en do)
SH)O
Af eqm.
AH>0 (). SH0
Vopous (at subimehon
temp.)
Sou'd iquid
At eq" Rat of subi'mahom Rake of depoibon.
(exo).
Ig (s)
Temp * Tenp. < Ieg Camphor (s) Campour (vepous)
(4a0)
Hthn ‘ (aG <0) Hething NH (s) NHyel (vap oun ).
fheesing ‘ (44<0)
fneuing 9 At e_m, inten ih iolct Colour (T, vap)) renainu Aame..
(endo)
AH)0
. Ha0 (sotid) Ha0 (Uguid) (at 0e)2
(04o). : Colous halogens
(eno)
6 Pale Yellow
Colows due to
Temp < o'e Temp >0'c el, ranib'n of e
greenish yelhw
H,o ( s ) ’ H,0 () redd'th brown (red) .o
(compl
Tom- sponmtan haneo ws. mlhing jasks.
factors afehing ?
Lp.
i) Sold Vapou
ApontanesMs.
* frezing faoka. Peyt Aubli'mabon ‘
Pext ‘ Aubli'mahon deposi h'on ‘
AH>O
Vapow
AH <O
sahom. Rate of condesahon.
At eqm, Rase of vapouu
costant
At costant emp.
Vapous Preswne
Preswe oß vapoy lig uid ahen ki'quid ano
Vapour are in quibum,
o facrs afteching Vapowr Bessne
Ve. ’ tenp. dep endant VP & Temp
A
ve (VP): A6) e
(BP): A<82e
Tenp temp.
Boiling
Point
2.303R
hee f, and , ae vapos pttemwe at
and T, tempuahire Tesp.
d (ln P)
dT RT2 oio hen åe
(6) VP
Snter moteular
attrachom
Volable
VP ‘ Snhesmal euas ature
boiling Point 4 a
, Volehve
Velable
solvent soute
ve of Aon maybe ehang
(ve) due to mixing
NO, H10 + HNO,
[pomenibophnol|
Snha- H-bmd Snes H-bond
VP ‘
lalcohol bneaks H-bmd
Exenal Presune. vP
(AH>O)
Amount prepuny Helhing (at malhing point cf
auLea () Solid iquid Cyshalline solid ).
frcinq (BH co)
AF equii bium,
Roie f malhing (yuin) - Rae os reeaing.
Volahle iqid volakle
AF maing point of enystalline (ohd
(Solvent ) free xing print of iyuid.
NoTmal
facos alkehing
Sea (ve).
wats wats i Exnal prLsWe :
Solid
iquid (expansin) Melhing Eat. P‘
o.I H Na cl (e) 0. 0S M 0.01 M
(ve) v'quid (eon hachn )
mthng e
D.2 mole in
0. 03 mole.
0. mole Ex : watks (soid) Was (liquid)
HË0 H10 + Na cl (susfece ka1sen) Ice
(due to in -dipole Conhhachon
in kenachon) igh deni
&+
Vacant fxpansion H-o
A
Jpace
* (v), H (ww densiy)
Solvent
Volahle ( 4 non- volakte (s)
, tethng of Helhing
porint
Tee ü) Smpunily
. volahle and P‘
Volahle +
Nom ’ Ve
Aolue
an solaed Ayskm , wats Fne ing
and in equil'bnum Pornt
(at o'e )
and mas of Hao Fr zing foint: The tmp. at which Ve (4) bcsmes
Mass oh ce
eons tant equal to VP. ().
iy Tempuahre. (en do)
SH)O
Af eqm.
AH>0 (). SH0
Vopous (at subimehon
temp.)
Sou'd iquid
At eq" Rat of subi'mahom Rake of depoibon.
(exo).
Ig (s)
Temp * Tenp. < Ieg Camphor (s) Campour (vepous)
(4a0)
Hthn ‘ (aG <0) Hething NH (s) NHyel (vap oun ).
fheesing ‘ (44<0)
fneuing 9 At e_m, inten ih iolct Colour (T, vap)) renainu Aame..
(endo)
AH)0
. Ha0 (sotid) Ha0 (Uguid) (at 0e)2
(04o). : Colous halogens
(eno)
6 Pale Yellow
Colows due to
Temp < o'e Temp >0'c el, ranib'n of e
greenish yelhw
H,o ( s ) ’ H,0 () redd'th brown (red) .o
(compl
Tom- sponmtan haneo ws. mlhing jasks.
factors afehing ?
Lp.
i) Sold Vapou
ApontanesMs.
* frezing faoka. Peyt Aubli'mabon ‘
Pext ‘ Aubli'mahon deposi h'on ‘
