Spectrometric Identification of Organic Compounds 8th Edition by Silverstein | Complete Study Guide & Answer Key

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compounds-8th-edition-silverstein-all-8-chapters-covered


SOLUTION MANUAL
All Chapters Included

,Answers for Student Exercises 1.1 to 1.5 1

Atom Type # of Atoms Mass Total Mass
Hydrogen 22 1.00783 22.17226
a
Carbon 10 12.00000 120.00000
Nitrogen 0 14.0031 0.00000
3-ethyloctane Oxygen 0 15.9949 0.00000
C10H22
Sulfur 0 31.9721 0.00000
C n H m X xN y O z IHD Bromine 0 78.9183 0.00000
Index = (n) - (m/2) - (x/2) + (y/2) + 1 = 0 Exact Mass 142.17226

- (C2H5 )

Rule 3



- (C5H11 )

Rule 3


H - (CH2=CH2)

Rule 9

b Atom Type # of Atoms Mass Total Mass
Hydrogen 18 1.00783 18.14094
Carbon 10 12.00000 120.00000
Nitrogen 0 14.0031 0.00000
3-butylcyclohex-1-ene Oxygen 0 15.9949 0.00000
C10H18 Sulfur 0 31.9721 0.00000
C nH m X x N y O z IHD Bromine 0 78.9183 0.00000
Index = (n) - (m/2) - (x/2) + (y/2) + 1 = 2 Exact Mass 138.14094



or




- (C4H9 )
Rule 5 and 6



- (CH2=CH2)
Rule 6



- (C3H7 )

Rule 3

, Answers for Student Exercises 1.1 to 1.5 2

O Atom Type # of Atoms Mass Total Mass
c Hydrogen 18 1.00783 18.14094
Carbon 13 12.00000 156.00000
Nitrogen 0 14.0031 0.00000
2-methyl-1-phenylhexan-1-one Oxygen 1 15.9949 15.99490
C13H18O Sulfur 0 31.9721 0.00000
C n H m X xN y O z IHD Bromine 0 78.9183 0.00000
Index = (n) - (m/2) - (x/2) + (y/2) + 1 = 5 Exact Mass 190.13584
O O O
- (C6H13 )

Rule 8
O O
- (C6H5 )
Rule 8

H
O - (C4H8) O OH

Rule 9 H

O
- (CO)
Rule 8+9

Atom Type # of Atoms Mass Total Mass
d Hydrogen 22 1.00783 22.17226
Carbon 11 12.00000 132.00000
(E)-undec-3-ene
C11 H22 Nitrogen 0 14.0031 0.00000
Oxygen 0 15.9949 0.00000
Sulfur 0 31.9721 0.00000
CnHmXxNyOz IHD Bromine 0 78.9183 0.00000
Index = (n) - (m/2) - (x/2) + (y/2) + 1 = 1 Exact Mass 154.17226



or



- (CH3)
Rule 5


- (C6H13)
Rule 5

H
- (C7H14)
Rule 9