TEST BANK for Organic Chemistry
6th Edition Smith /
All Chapters 1 - 29 / Full Complete
Page 1
,Chapter 1 Structure and Bonding Chapter
2 Acids and Bases
Chapter 3 Introduction to Organic Molecules and Functional Groups Chapter 4
Alkanes
Chapter 5 Stereochemistry
Chapter 6 Understanding Organic Reactions
Chapter 7 Alkyl Halides and Nucleophilic Substitution
Chapter 8 Alkyl Halides and Elimination Reactions Chapter
9 Alcohols, Ethers, and Related Compounds Chapter 10
Alkenes and Addition Reactions
Chapter 11 Alkynes and Synthesis Chapter
12 Oxidation and Reduction Spectroscopy
A Mass Spectrometry Spectroscopy B
Infrared Spectroscopy
Spectroscopy C Nuclear Magnetic Resonance Spectroscopy Chapter 13
Radical Reactions
Chapter 14 Conjugation, Resonance, and Dienes Chapter 15
Benzene and Aromatic Compounds Chapter 16 Reactions of
Aromatic Compounds
Chapter 17 Introduction to Carbonyl Chemistry: Organometallic Reagents;
Oxidation and Reduction
Chapter 18 Aldehydes and Ketones—Nucleophilic Addition Chapter 19
Carboxylic Acids and Nitriles
Chapter 20 Carboxylic Acids and Their Derivatives- Nucleophilic Acyl Substitution
Chapter 21 Substitution Reactions of Carbonyl Compounds at the α-Carbon
Chapter 22 Carbonyl Condensation Reactions
Chapter 23 Amines
Chapter 24 Carbon-Carbon Bond-Forming Reactions in Organic Synthesis Chapter
25 Pericyclic Reactions
Chapter 26 Carbohydrates
Chapter 27 Amino Acids and Proteins
Chapter 28 Synthetic Polymers Chapter 29
Lipids (Available online)
Page 2
, Chapter 1: Structure and Bonding
1. What is the ground-state electronic configuration of a carbon atom?
A) 1s2, 2s2, 2p5 B) 1s2, 2s2, 2p2 C) 1s2, 2s2, 2p6 D) 1s2, 2s2, 2p4
2. What is the ground-state electronic configuration of a fluorine atom?
A) 1s2, 2s2, 2p2 B) 1s2, 2s2, 2p3 C) 1s2, 2s2, 2p4 D) 1s2, 2s2, 2p5
3. What is the ground-state electronic configuration of a magnesium cation (Mg2+)?
A) 1s2, 2s2, 2p6 C) 1s2, 2s2, 2p6, 3s2
B) 1s2, 2s2, 2p6, 3s1 D) 1s2, 2s2, 2p6, 3s2, 3p2
4. What is the ground-state electronic configuration of a chlorine anion (Cl—)?
A) 1s2, 2s2, 2p6 C) 1s2, 2s2, 2p6, 3s2, 3p5
B) 1s2, 2s2, 2p6, 3s2, 3p6 D) 1s2, 2s2, 2p6, 3s2, 3p4
5. Which of the following statements about valence electrons is true?
A) They are the most tightly held electrons.
B) They do not participate in chemical reactions.
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, Chapter 1: Structure and Bonding
C) They are the outermost electrons.
D) They reveal the period number of a second-row element.
6. Which of the following statements about bonding is true?
A) Covalent bonds result from the transfer of electrons from one element to another.
B) Ionic bonds result from the transfer of electrons from a metal to a non-metal.
C) Ionic bonds result from the sharing of electrons between two non-metals.
D) Covalent bonds result from the sharing of electrons between two metals.
7. Which of the following would you expect to have ionic bonds?
A) CO B) FBr C) NF3 D) NaCl
8. Which of the following molecules has nonpolar covalent bonds?
A) HCl B) N2 C) CHCl3 D) NO
9. Which of the following molecules contain both covalent and ionic bonds?
A) I, II B) I, IV C) II, III D) II, IV
10. Arrange the following bonds in decreasing order of ionic character, putting the most
ionic first.
A) I > II > III > IV C) IV > III > II > I
B) IV > II > I > III D) IV > II > III > I
11. Which of the following statements correctly describes the typical number of bonds for
carbon, nitrogen, and oxygen in most neutral organic molecules?
A) Carbon forms 4 covalent bonds, nitrogen forms 2 covalent bonds and oxygen forms
3 covalent bonds.
B) Carbon forms 4 covalent bonds, nitrogen forms 3 covalent bonds and oxygen forms
2 covalent bonds.
Page 4
6th Edition Smith /
All Chapters 1 - 29 / Full Complete
Page 1
,Chapter 1 Structure and Bonding Chapter
2 Acids and Bases
Chapter 3 Introduction to Organic Molecules and Functional Groups Chapter 4
Alkanes
Chapter 5 Stereochemistry
Chapter 6 Understanding Organic Reactions
Chapter 7 Alkyl Halides and Nucleophilic Substitution
Chapter 8 Alkyl Halides and Elimination Reactions Chapter
9 Alcohols, Ethers, and Related Compounds Chapter 10
Alkenes and Addition Reactions
Chapter 11 Alkynes and Synthesis Chapter
12 Oxidation and Reduction Spectroscopy
A Mass Spectrometry Spectroscopy B
Infrared Spectroscopy
Spectroscopy C Nuclear Magnetic Resonance Spectroscopy Chapter 13
Radical Reactions
Chapter 14 Conjugation, Resonance, and Dienes Chapter 15
Benzene and Aromatic Compounds Chapter 16 Reactions of
Aromatic Compounds
Chapter 17 Introduction to Carbonyl Chemistry: Organometallic Reagents;
Oxidation and Reduction
Chapter 18 Aldehydes and Ketones—Nucleophilic Addition Chapter 19
Carboxylic Acids and Nitriles
Chapter 20 Carboxylic Acids and Their Derivatives- Nucleophilic Acyl Substitution
Chapter 21 Substitution Reactions of Carbonyl Compounds at the α-Carbon
Chapter 22 Carbonyl Condensation Reactions
Chapter 23 Amines
Chapter 24 Carbon-Carbon Bond-Forming Reactions in Organic Synthesis Chapter
25 Pericyclic Reactions
Chapter 26 Carbohydrates
Chapter 27 Amino Acids and Proteins
Chapter 28 Synthetic Polymers Chapter 29
Lipids (Available online)
Page 2
, Chapter 1: Structure and Bonding
1. What is the ground-state electronic configuration of a carbon atom?
A) 1s2, 2s2, 2p5 B) 1s2, 2s2, 2p2 C) 1s2, 2s2, 2p6 D) 1s2, 2s2, 2p4
2. What is the ground-state electronic configuration of a fluorine atom?
A) 1s2, 2s2, 2p2 B) 1s2, 2s2, 2p3 C) 1s2, 2s2, 2p4 D) 1s2, 2s2, 2p5
3. What is the ground-state electronic configuration of a magnesium cation (Mg2+)?
A) 1s2, 2s2, 2p6 C) 1s2, 2s2, 2p6, 3s2
B) 1s2, 2s2, 2p6, 3s1 D) 1s2, 2s2, 2p6, 3s2, 3p2
4. What is the ground-state electronic configuration of a chlorine anion (Cl—)?
A) 1s2, 2s2, 2p6 C) 1s2, 2s2, 2p6, 3s2, 3p5
B) 1s2, 2s2, 2p6, 3s2, 3p6 D) 1s2, 2s2, 2p6, 3s2, 3p4
5. Which of the following statements about valence electrons is true?
A) They are the most tightly held electrons.
B) They do not participate in chemical reactions.
Page 3
, Chapter 1: Structure and Bonding
C) They are the outermost electrons.
D) They reveal the period number of a second-row element.
6. Which of the following statements about bonding is true?
A) Covalent bonds result from the transfer of electrons from one element to another.
B) Ionic bonds result from the transfer of electrons from a metal to a non-metal.
C) Ionic bonds result from the sharing of electrons between two non-metals.
D) Covalent bonds result from the sharing of electrons between two metals.
7. Which of the following would you expect to have ionic bonds?
A) CO B) FBr C) NF3 D) NaCl
8. Which of the following molecules has nonpolar covalent bonds?
A) HCl B) N2 C) CHCl3 D) NO
9. Which of the following molecules contain both covalent and ionic bonds?
A) I, II B) I, IV C) II, III D) II, IV
10. Arrange the following bonds in decreasing order of ionic character, putting the most
ionic first.
A) I > II > III > IV C) IV > III > II > I
B) IV > II > I > III D) IV > II > III > I
11. Which of the following statements correctly describes the typical number of bonds for
carbon, nitrogen, and oxygen in most neutral organic molecules?
A) Carbon forms 4 covalent bonds, nitrogen forms 2 covalent bonds and oxygen forms
3 covalent bonds.
B) Carbon forms 4 covalent bonds, nitrogen forms 3 covalent bonds and oxygen forms
2 covalent bonds.
Page 4
