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Class notes Dental Materials

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This document discusses metals and alloys used in dentistry, starting with the definition of alloys as mixtures of metallic and nonmetallic elements with improved properties. It categorizes alloys into cast metal alloys (for inlays, crowns, bridges, dentures), wrought alloys (for orthodontic wires, endodontic files, implants), and solders (for joining metals). The PDF explains the crystal structures and grains of alloys, noting that smaller grain sizes are desirable for uniform properties and can be achieved through quenching or seeding. It lists major elements in dental alloys, dividing them into noble metal elements (gold, palladium, platinum) and base metal elements (copper, silver, zinc, nickel, cobalt, titanium, etc.), detailing the properties of each. The ADA classification of dental casting alloys is provided: high noble alloys (≥60% noble, ≥40% gold), noble alloys (≥25% noble), and base metal alloys (25% noble). Each class is described with examples, properties, and uses. The PDF also covers properties of alloys such as color, melting range (liquidus and solidus), density, strength, hardness, modulus, and biocompatibility (linked to corrosion). Ceramic bonding casting alloys are discussed, emphasizing the need for an oxide layer to bond with ceramic and the importance of matching thermal expansion coefficients. Problems with ceramic-alloy bonding like oxide color, greening, and debonding are listed. The document also explains wrought alloys (mechanically altered into shapes like wires) and solders (alloys used to join metals, with specific melting ranges and flow properties). Finally, the dental casting process is outlined, involving wax pattern, investing, burnout, casting, and recovery, with a note on investment materials (gypsum-bonded, phosphate-bonded, silica-bonded) and their functions.

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Casting Alloys, Wrought Alloys and Solders:

Alloys:
➢ Alloys are mixtures of metallic and nonmetallic elements that have better
properties for dental restorations than any single element
➢ Alloys have been used in dentistry for thousands of years to replace natural
tooth structure.
➢ The earliest restorations used pure gold because it was very easy to purify,
melt, and manipulate
○ Gold in foil form probably was used first as a dental restorative
material several thousand years ago.

Most Common Alloys Used in Dentistry:


➢ Cast Metal Alloys: ➢ Wrought Alloys: ➢ Solders:

- For inlays, onlays, - For orthodontic wires, - a molten filler metal
crowns, bridges endodontic files, and that is used to connect
- Partial or complete implants pieces of metal.
denture bases
- Denture bases

, Crystal Structures and Grains of Alloys:
➢ Dental alloys like ice, salt, sugar, or many other solids have a crystal
structure
➢ When a molten (liquid) alloy freezes, crystals (grains) form and grow as the
alloy cools
➢ Each crystal consists of a crystal lattice of metal atoms.
➢ The boundaries where individual crystals meet are called grain boundaries.




Grain Size:
➢ A small grain size is generally more desirable as it ensures uniform
properties of the alloy
➢ Metals with finer grain structure are generally harder and have higher
values of yield stress than those with coarser grain structure.
➢ Achieve Grain Structure By:
○ Quenching: Rapid cooling of the molten metal or alloy following
casting.
○ Refined Grain Structure: seeding the molten material with an
additive metal (iridium and indium) which forms nuclei for
crystallization.


Grain Structure:
➢ Significantly altered by mechanical forces
○ Wrought Alloy: If the alloy is rolled into a sheet or drawn into a
wire and the grain structure takes on a fibrous appearance.
➢ Heating of the alloy after casting or mechanical work may change its grain structure
○ These changes may lead to significant changes in the
properties of the alloy.
○ Ex: heat treatment of Au-Cu ally can produce a stronger
alloy.
■ The copper atoms can be induced to change
lattice positions depending on how the alloy is
cast (or reheated) and cooled.


Major Elements In Dental Alloys:
1. Noble Metal Elements
2. Base Metal Elements

1.Noble Metal Elements:
➢ Defined by their resistance to corrosion even under extreme conditions that occur in the oral
cavity
➢ Noble metals are expensive simply because they are rare (precious)
➢ Out of 7 elements, the 3 mainly used in dentistry are gold, palladium, platinum.

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December 5, 2025
Number of pages
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2024/2025
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Arief cahyanto
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