Mechanism of
Organic
Reactions
For world of competitions
By
AJNISH GUPTA & BHARTI GUPTA
Professor of Organic Chemistry
(i)
, Alkene & Alkyne
Unit
1
Alkene and Alkynes
Objective
This unit give you a n understa nding of “ Genera l
Orga nic chemistry of alkene & Alkyne” and covers
following topics:
Reaction of HX
Reaction of H2 O/H+
Reaction of ROH/H+
Reaction of X2
Reaction of X-X’
Reaction of NOX
Reaction of HOX
Oximercuration-Demercuration
Alkoxymercuration-Demercuration
Hydroboration-Oxidation
Organic Chemistry is easy by 1
www.CoachMe.co.in
, Alkene & Alkyne
Exercise
01
Subjective Approach
You can’t learn organic chemistry because there’s too much of
it. You can learn trivial things like name of compounds but that
doesn’t help you to understand the principle behind the subject.
You have to understand the principle because the only way to
tackle organic chemistry is to learn to work it out. That is why we
are first providing you some questions so that your understanding
about the topic should be increased. These problems should be set
you on your way but they are not the end of the journey as you
begin your journey to understand organic chemistry.
The problem would be of little use to you when you could not
check your answers. For the maximum benefit, you need to solve
all the problems without looking the answers. Then you should
compare your answers or suggestions with ours before going to
next chapter. If any answer is mismatch then darken those question
numbers with red pen and again have a micorscopic look over it
and its theory and correct it before proceeding further. Here starts
the first set of 55 questions
1. What are the general types of organic reactions. Comment over
it by taking simple alphabets without any reaction.
2. Wha t is rea gent. Na me the types of reagent generally we
encounter in organic chemistry.
2 Organic Chemistry is easy by
www.CoachMe.co.in
, Alkene & Alkyne
3. What is a n electrophile a nd what a re the fa ctors which
increases the electrophilic nature of any molecule.
4. What is nucleophile and what a re the factors which Increases
the nucleophilic character of any molecule.
5. What is free radical and what a re the factors which increases
the free radical formation easy in a ny molecule.
6. What is leaving group and what are the factors which increases
the leaving group character of a ny species.
7. Write the order of nucleophilic character in given molecule.
O O
OH – , Ph–O – , CH 3 –C–O – , CH 3 –S–O –
O
I – , Br– , Cl – , F – NH 3 , H 2 O
8. Write in decreasing order of leaving group character in given
molecules. O O
OH – , Ph–O – , CH 3 –C–O – , CH 3 –S–O –
O
– – – –
I , Br , Cl , F NH 3 , H 2 O
9. What are solvents. How they are classified. Write example of
each types.
10. What is the basic difference between base, nucleophile and
ligand. Explain with example.
11. What is the general chemical reaction of alkene & alkyne.
12. What is Markownikoff rule.
13. What is the basic concept behind Markownikoff rule. Give an
example which violate this rule.
14. Write 2 chemical test which can distinguish alkene from alkanes.
15. What is Baeyer’s reagent. How is it importa nt in organic
chemistry.
16. Wha t is genera l hydra tion rea ction of alkene. Give the
mechanism of hydration of propene.
Organic Chemistry is easy by 3
www.CoachMe.co.in
Organic
Reactions
For world of competitions
By
AJNISH GUPTA & BHARTI GUPTA
Professor of Organic Chemistry
(i)
, Alkene & Alkyne
Unit
1
Alkene and Alkynes
Objective
This unit give you a n understa nding of “ Genera l
Orga nic chemistry of alkene & Alkyne” and covers
following topics:
Reaction of HX
Reaction of H2 O/H+
Reaction of ROH/H+
Reaction of X2
Reaction of X-X’
Reaction of NOX
Reaction of HOX
Oximercuration-Demercuration
Alkoxymercuration-Demercuration
Hydroboration-Oxidation
Organic Chemistry is easy by 1
www.CoachMe.co.in
, Alkene & Alkyne
Exercise
01
Subjective Approach
You can’t learn organic chemistry because there’s too much of
it. You can learn trivial things like name of compounds but that
doesn’t help you to understand the principle behind the subject.
You have to understand the principle because the only way to
tackle organic chemistry is to learn to work it out. That is why we
are first providing you some questions so that your understanding
about the topic should be increased. These problems should be set
you on your way but they are not the end of the journey as you
begin your journey to understand organic chemistry.
The problem would be of little use to you when you could not
check your answers. For the maximum benefit, you need to solve
all the problems without looking the answers. Then you should
compare your answers or suggestions with ours before going to
next chapter. If any answer is mismatch then darken those question
numbers with red pen and again have a micorscopic look over it
and its theory and correct it before proceeding further. Here starts
the first set of 55 questions
1. What are the general types of organic reactions. Comment over
it by taking simple alphabets without any reaction.
2. Wha t is rea gent. Na me the types of reagent generally we
encounter in organic chemistry.
2 Organic Chemistry is easy by
www.CoachMe.co.in
, Alkene & Alkyne
3. What is a n electrophile a nd what a re the fa ctors which
increases the electrophilic nature of any molecule.
4. What is nucleophile and what a re the factors which Increases
the nucleophilic character of any molecule.
5. What is free radical and what a re the factors which increases
the free radical formation easy in a ny molecule.
6. What is leaving group and what are the factors which increases
the leaving group character of a ny species.
7. Write the order of nucleophilic character in given molecule.
O O
OH – , Ph–O – , CH 3 –C–O – , CH 3 –S–O –
O
I – , Br– , Cl – , F – NH 3 , H 2 O
8. Write in decreasing order of leaving group character in given
molecules. O O
OH – , Ph–O – , CH 3 –C–O – , CH 3 –S–O –
O
– – – –
I , Br , Cl , F NH 3 , H 2 O
9. What are solvents. How they are classified. Write example of
each types.
10. What is the basic difference between base, nucleophile and
ligand. Explain with example.
11. What is the general chemical reaction of alkene & alkyne.
12. What is Markownikoff rule.
13. What is the basic concept behind Markownikoff rule. Give an
example which violate this rule.
14. Write 2 chemical test which can distinguish alkene from alkanes.
15. What is Baeyer’s reagent. How is it importa nt in organic
chemistry.
16. Wha t is genera l hydra tion rea ction of alkene. Give the
mechanism of hydration of propene.
Organic Chemistry is easy by 3
www.CoachMe.co.in
