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AQA-7404-1-CHEMISTRY QUESTION PAPER 1-AS LEVEL-INORGANIC AND PHYSICAL CHEMISTRY-14May24.ALL THE BEST

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AQA-7404-1-CHEMISTRY QUESTION PAPER 1-AS LEVEL-INORGANIC AND PHYSICAL CHEMISTRY-14May24. 0 1 A student does a series of reactions with aqueous solutions of some potassium halides (P, Q and R) of equal concentration. Each solution contains a different halide ion (chloride, bromide or iodide). The student adds 3 drops of bromine water to 3 drops of each aqueous solution of potassium halide. The student also adds 3 drops of the bromine water to 3 drops of water. Table 1 shows the student’s observations. Table 1 Observation when 3 drops of bromine water are added Solution P Orange solution Solution Q Brown solution Solution R Orange solution Water Orange solution 0 1 . 1 Identify the halide ion present in Q. Give the ionic equation for the reaction that occurs when bromine water is added to Q. [2 marks] Halide ion in Q Ionic equation 000002 Page 2 of 28 CHEMISTRY 3 *03* Turn over ► IB/M/Jun24/7404/1 Do not write outside the box 0 1 . 2 Explain, in terms of oxidising ability, why the observations from these reactions do not allow the student to identify the halide ion present in P and the halide ion present in R. [2 marks] 0 1 . 3 The student does a second experiment to determine the halide ion in each of P and R. The student adds a few drops of aqueous silver nitrate solution to 2 cm3 of each potassium halide solution. Table 2 shows the student’s observations. Table 2 Student’s Observation P Precipitate formed R Precipitate formed Describe a further chemical test that the student can complete on the precipitates formed to identify the halide ion present in P and the halide ion present in R. Describe how the observations

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000001




AQA
Please write clearly in block capitals.

Centre number Candidate number


Surname

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I declare this is my own work.


AS



Y
CHEMISTRY
Paper 1 Inorganic and Physical Chemistry TR
Tuesday 14 May 2024 Morning Time allowed: 1 hour 30 minutes
IS
Materials
For this paper you must have: For Examiner’s Use
EM


• the Periodic Table/Data Sheet, provided as an insert (enclosed)
• a ruler with millimetre measurements Question Mark
• a scientific calculator, which you are expected to use where appropriate. 1
2
Instructions
3
• Use black ink or black ball-point pen.
H



• Fill in the boxes at the top of this page. 4
• Answer all questions. 5
• You must answer the questions in the spaces provided. Do not write outside
C




6
the box around each page or on blank pages.
7
• If you need extra space for your answer(s), use the lined pages at the end of
this book. Write the question number against your answer(s). 8
• All working must be shown. 9
• Do all rough work in this book. Cross through any work you do not
Section B
want to be marked.
TOTAL
Information
• The marks for questions are shown in brackets.
• The maximum mark for this paper is 80.

Advice
You are advised to spend about 65 minutes on Section A and 25 minutes on Section B.




IB/M/Jun24/G4001/V7 7404/1
Page 1 of 28

,000002

2
Do not write
outside the
Section A box


Answer all questions in this section.


0 1 A student does a series of reactions with aqueous solutions of some
potassium halides (P, Q and R) of equal concentration. Each solution contains a
different halide ion (chloride, bromide or iodide).

The student adds 3 drops of bromine water to 3 drops of each aqueous solution of
potassium halide. The student also adds 3 drops of the bromine water to
3 drops of water.

Table 1 shows the student’s observations.

Table 1

Observation when 3 drops




Y
of bromine water are added

Solution P Orange solution

Solution Q

Solution R
TR
Brown solution

Orange solution
IS
Water Orange solution
EM


0 1 . 1 Identify the halide ion present in Q.

Give the ionic equation for the reaction that occurs when bromine water is added to Q.
[2 marks]

Halide ion in Q
H



Ionic equation
C




*02*
IB/M/Jun24/7404/1
Page 2 of 28

, 000003

3
Do not write
outside the
0 1 . 2 box
Explain, in terms of oxidising ability, why the observations from these reactions
do not allow the student to identify the halide ion present in P and the halide ion
present in R.
[2 marks]




0 1 . 3 The student does a second experiment to determine the halide ion in each of P and R.

The student adds a few drops of aqueous silver nitrate solution to
2 cm3 of each potassium halide solution.




Y
Table 2 shows the student’s observations.

Table 2

TR
Student’s Observation


P Precipitate formed
IS
R Precipitate formed
EM


Describe a further chemical test that the student can complete on the precipitates
formed to identify the halide ion present in P and the halide ion present in R.

Describe how the observations from this test can be used to identify the halide ion
present in P and the halide ion present in R.
H



[3 marks]
C




7



Turn over for the next question


Turn over ►


*03*
IB/M/Jun24/7404/1
Page 3 of 28

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